Hydrocarbon polyl gem-bis(t-alkylperoxy)alkanoates derived from

Details Hydrocarbon polyl gem-bis(t-alkylperoxy)alkanoates derived from Hydrocarbon polyl gem-bis(t-alkylperoxy)alkanoates derived from

1977-05-31

1981-09-08

Trousof, Natalie

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2604107, 560129, 252426, C07C17906

Patent

active

042883792

ABSTRACT:
The title compounds are useful vinyl polymerization initiators of high thermal stability and correspond to the formula: ##STR1## wherein R is an x-valent hydrocarbon whose chain length can be interrupted by one or more ether linkages, R' is an aliphatic moiety of 1 to about 10 carbon atoms, R" is a tertiary hydrocarbon, and x is an integer of at least 2.

REFERENCES:
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patent: 3630960 (1971-12-01), Chetakian
patent: 3649546 (1972-03-01), McCloskey et al.
patent: 3964950 (1976-06-01), Boles
patent: 4052464 (1977-10-01), Priddy
Kirk-Othmer "Enc. of Chem. Tech." 2nd Ed. vol. 1, pp. 153 and 158.
Hattori, Seiji et al. "Peroxyketals" Japan Kokai 74,110,617 dated Oct. 22, 1974, (See Chemical Abstracts vol. 82 (1975) #155,350f).
Pennwalt-Lucidol Preliminary Data Sheet, Product Bulletin R-233, No date.
Witco Chemical US Peroxy Division, Technical Bulletin USP-333, No date.
Cubbon, R.C.P. et al. "Organic Peroxides Containing Functional Groups" Pts. II and III, J. Chem. Soc. (1968) pp. 2983-2988.

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