Production of cyclic ethers

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260338, 2603451, 26034611, 568402, C07D30708, C07D30706, C07D30904, C07D31304

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active

042883695

ABSTRACT:
A process for the preparation of cyclic ethers which comprises reacting an alkanediol in which the hydroxyl groups are separated by a chain of at least four carbon atoms in the liquid phase of a catalyst comprising a palladium salt and a copper salt, and recovering the cyclic ether thus formed by a separation step such as distillation. The reaction is carried out in a molecular oxygen gaseous atmosphere. A preferred catalyst is palladium chloride in combination with a copper salt such as cupric chloride or cupric nitrate.

REFERENCES:
M. Bartok et al., Acta Physica et Chemica, vol. 18, (1972), No. 3-4, pp. 207-211.
W. G. Lloyd, Jour. Org. Chem., (1967), pp. 2816-2819, vol. 32.

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