Chemical synthesis of stable and electroactive polypyrrole and r

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From ketone or ketene reactant

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528380, 528392, 528405, 528423, C08G 206, C08G 218

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active

049564447

ABSTRACT:
A simple chemical process for the simultaneous polymerization and oxidation of pyrrole, N-substituted pyrroles, and other heterocycles having five or six member rings by halogenic or organic electron acceptors. The polypyrrole-acceptor charge transfer complexes so produced are of high purity and are stable in the atmosphere, in the presence of moisture and at elevated temperatures. The conductivities of the complexes are controllable between 30 ohm.sup.-1 cm.sup.-1 and 10.sup.-3 ohm-1 cm-1, depending on the type of acceptor used and the process conditions.

REFERENCES:
patent: 3574072 (1971-04-01), Louvar
patent: 4640749 (1987-02-01), Naarmann et al.
"Chemical Synthesis and Characterization of Polypyrrol-Chlorine Complex", Polymer, 1988, vol. 29, K. G. Neoh, T. C. Tan, and E. T. Kang, pp. 553-558.
"Stability of Chemically Synthesized Conducting Polypyrrole-Halogen Complexes in Acidic and Basic Solutions and Organic Solvents", Polymer Communications, vol. 30, 1989, K. G. Neoh et al., pp. 48-50.

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