Process for the production of a crystalline aluminosilicate zeol

Chemistry of inorganic compounds – Silicon or compound thereof – Oxygen containing

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423328, 423330, 502 77, C01B 3320

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045228000

ABSTRACT:
A method for making crystalline aluminosilicate ZSM-34 zeolites, useful as catalysts for making C.sub.2 -C.sub.4 -olefins from methanol, from a reaction mixture containing silicon, aluminum, sodium, potassium, and an organic template compound which is (i) a salt of an ammonium compound of di-, tri-, or tetra-ethanolamine or (ii) a mixture of at least one of diethanolamine and triethanolamine with certain lower alkanols, lower alkylene diols, or lower alkyl iodides, sulfates, or p-toluenesulfonates.

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L. W. Staples et al., Mineralogical Magazine, 32, 261-281, (1959).
R. M. Barrer FRS, Hydrothermal Chemistry of Zeolites, Academic Press, New York, 1982, pp. 204-205, 247.
A. Erdem & L. B. Sand, in "Proceedings of the 5th International Conference on Zeolites", (Ed. L. V. C. Rees), p. 64, Heyden London, 1980.

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