Molten carbonate type fuel cell

Chemistry: electrical current producing apparatus – product – and – Having earth feature

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429 16, 429 41, H01M 814

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active

049802488

ABSTRACT:
A molten carbonate type fuel cell with a stabilized battery characteristic over a long period of time by replenishing the electrolyte which has been consumed, and maintaining the electrolyte at a consistent composition, the fuel cell carrying, on at least one of the electrolytic layer at its side of the air electrode, the air electrode per se, and the structural members of the air electrode side gas chamber, a lithium-containing composite oxide which brings about chemical reaction, when a ratio of lithium (Li) to potassium (K) in the electrolyte reduces, to produce Li.sub.2 CO.sub.3 due to change in the ratios between lithium and other elements, during a period when the Li/K ratio between lithium and potassium in the electrolyte comprising mainly Li.sub.2 CO.sub.3 and K.sub.2 CO.sub.3 varies from 40/60 to 70/30 at a temperature range of from 600.degree. C. to 700.degree. C. in a gas atmosphere of the air electrode side.

REFERENCES:
patent: 4564567 (1986-01-01), Kucora et al.
patent: 4591538 (1986-05-01), Kunz
patent: 4643954 (1987-02-01), Smith
patent: 4797379 (1989-01-01), Patel et al.
Oak Ridge National Laboratory ORNL-6181, Thermodynamics of Chromium and Iron in Carbonate Salts at 650 by H. S. Hsu and J. H. Devan (May 1985).

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