Process for producing aromatic hydrocarbons

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By ring formation from nonring moiety – e.g. – aromatization,...

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585415, 585416, 423326, C07C 282

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052025136

ABSTRACT:
A process for producing modified crystalline galloalumino silicate having the ZSM-5 crystal structure, and a process for producing aromatic hydrocarbons by the use of a catalyst containing the above modified crystalline galloalumino silicate are disclosed. The modified crystalline galloalumino silicate having the ZSM-5 type crystal structure is produced contacting with a 0.1-2N aqueous alkali hydroxide, followed by calcining galloalumino silicate having the ZSM-5 type crystal structure as obtained by the hydrothermic reaction, at a temperature of 700.degree. to 1,000.degree. C. The aromatic hydrocarbons are produced by contacting hydrocarbons having 2 to 12 carbon atoms with a catalyst containing the above modified crystalline galloalumino silicate.

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Kentgens et al. Chem. Physics Letters, vol. 176, (3,4) pp. 399-403) (Jan. 1991).
Bayense et al. J.C.S. Chem. Communication 1989, pp. 1292-1293 (1989).

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