Process for producing optically active alcohols

Details Process for producing optically active alcohols Process for producing optically active alcohols

1992-03-23

1993-04-13

Cintins, Marianne M.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568813, 568814, 568822, 568825, 568832, 568835, 568838, 568874, 568880, 549 13, C07C 29136, C07C 3506, C07C 3508

Patent

active

052025020

ABSTRACT:
A chemically and optically pure B-halodiiso-2-ethylapopinocampheylborane of essentially 100% ee represented by the formula: ##STR1## wherein B is borane and X is halo, and a process of using such for the production of optically active alcohols.

REFERENCES:
patent: 4772752 (1988-09-01), Brown
H. C. Brown et al., J. Org. Chem., 1986, 51, 432-439.
H. C. Brown et al., J. Org. Chem., 1988, 53, 5513-5518.
H. C. Brown et al., J. Am. Chem. Soc., 1988, 110, 1539-1546.
H. C. Brown et al., J. Org. Chem., 1984, 4089-4091.
M. Mark Midland et al., J. Am. Chem. Soc., 1979, 101:9,2352-55.
H. C. Brown, J. Org. Chem., 1989, 54, 4504-4511.

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