Process to insecticide intermediate

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

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C07C 1726

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044658796

ABSTRACT:
A 3-halo-2-methylphenylmagnesium halide is cross-coupled with a halobenzene under heterogeneous conditions using palladium metal as catalyst, producing a 3-halo-2-methyl[1,1'-biphenyl].

REFERENCES:
patent: 4214004 (1980-07-01), Plummer
patent: 4238505 (1980-12-01), Engel
M. Kumada, Pure and Appl. Chem., 52, 669 (1980).
Mitchell et al., Can. J. Chem., 58, 2584 (1980).
Sekiya et al., J. Organometallic Chem., 118, 349 (1976).
Tet. Lett., 21, 845 (1980).

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