Super ionic conductive glass

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Include electrolyte chemically specified and method

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429104, 501 55, 501 63, 501 68, 501 72, 501 73, H01M 618

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active

044657447

ABSTRACT:
An ionically conducting glass for use as a solid electrolyte in a power or secondary cell containing an alkali metal-containing anode and a cathode separated by an alkali metal ion conducting glass having an ionic transference number of unity and the general formula: A.sub.1+x D.sub.2-x/3 Si.sub.x P.sub.3-x O.sub.12-2x/3, wherein A is a network modifier for the glass and is an alkali metal of the anode, D is an intermediate for the glass and is selected from the class consisting of Zr, Ti, Ge, Al, Sb, Be, and Zn and X is in the range of from 2.25 to 3.0. Of the alkali metals, Na and Li are preferred and of the intermediate, Zr, Ti and Ge are preferred.

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patent: 4124739 (1978-11-01), Sudworth
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ANL 76-8, Weiner, "The Sodium/Sulfur Battery: A Progress Report", pp. B-219-B-225, 1976.
DOE/ET/25103-TL, Final Report, Contract No. DE-AC02-76ET-25103, pp. 3-10, 32-49 and 102-106.
Souquet, "Electrochemical Properties of Ionically Conductive Glasses", 1980.

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