Aqueous suspension polymerization of 1,3-butadiene to produce sy

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526 91, 526 93, 526140, 526141, 526142, 526144, 526335, C08F 218, C08F13606

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053469712

ABSTRACT:
A process for producing polybutadiene essentially consisted of syndiotactic-1,2-polybutadiene in an aqueous medium includes a step off polymerizing diene essentially consisted of 1,3-butadiene in the presence of: (A) a catalyst composition including (a) a transition metal compound, and (b) an organometallic compound which includes a metal selected from the elements consisting off groups 1, 2, 12, and 13 of Periodic Table; (B) an initiator comprising at least one component selected from a group consisting of carbon disulfide, an isothiocyanate compound, and a xanthogenic compound; and (C) an inert organic liquid having a density of at least 1.10, thereby resultant particles of syndiotactic-1,2-polybutadiene have a diameter up to 2 min.

REFERENCES:
patent: 5011896 (1991-04-01), Bell et al.
Riddick et al, Organic Solvents (3rd ed.) Wiley-Interscience, N.Y., pp. 66, 348 (1970).

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