Means and method for the electrochemical carbonylation of nitrob

Details Means and method for the electrochemical carbonylation of nitrob Means and method for the electrochemical carbonylation of nitrob

1985-02-07

1986-01-07

Niebling, John F.

Chemistry: electrical and wave energy

Processes and products

C25C 300

Patent

active

045632545

ABSTRACT:
Apparatus for the carbonylation of nitrobenzene or 2-5 dinitrotoluene with carbon dioxide to provide a product includes a housing which contains an electrolyte solution having a non-aqueous electrolyte containing a supporting electrolyte. A membrane divides the housing into two sections while permitting ions to move between the two sections. Carbon dioxide and nitrobenzene or 2-5 dinitrotoluene are provided to the housing. A d.c. voltage is provided across the electrolyte solution in the two sections of the housing, to cooperate in a reaction of the carbon dioxide, the nitrobenzene or the 2-5 dinitrotoluene and the electrolyte solution to provide a chemical product.

REFERENCES:
patent: 4028201 (1977-07-01), Tyssee
patent: 4133726 (1979-01-01), Wagenknecht
Organic Electro Chemistry 2nd Ed. edited by Baizer et al. (1983) Dekker, pp. 295-304.

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