Process for the production of unsymmetrical tert-dialkyl ethers

Details Process for the production of unsymmetrical tert-dialkyl ethers Process for the production of unsymmetrical tert-dialkyl ethers

1991-12-30

1994-11-15

Mars, Howard T.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

C07C 4109

Patent

active

053649800

ABSTRACT:
A method for preparing unsymmetrical dialkyl ethers and derivatives thereof. The ethers are prepared by reacting a C.sub.1 to C.sub.3 aliphatic alcohol with a tertiary alcohol in the presence of a novel catalyst comprised of a transition metal pillared interlayered clay having generally separated layers wherein the interlayer distances are substantially greater than a precursor of the same but non-separated clay and wherein the product includes multimetallic pillars comprised of a cationic polymeric complex of the formula:

REFERENCES:
patent: 4605806 (1986-08-01), Ballantine et al.
patent: 5099072 (1992-03-01), Knifton

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