Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof
Patent
1978-06-19
1979-05-15
Phynes, Lucille M.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
From carboxylic acid or derivative thereof
528309, C08G 6330
Patent
active
041549210
ABSTRACT:
The formation of manganese-derivative scale in equipment involved in polyester manufacture is reduced by introduction of a sterically hindered benzoic acid in approximately stoichiometric amount. The acids include 2,6-dichloro-, 2,6-dimethyl- and 2,4,6-trimethylbenzoic acids. The scale is believed to be insoluble manganese terephthalate, presumably formed by reaction of manganese acetate catalyst generated as a result of a side reaction during the ester exchange reaction of dimethyl terephthalate with excess ethylene glycol. Preferably an alkali metal salt of an organic acid, such as sodium acetate or lithium acetate is also used to give a synergistic effect in combination with the hindered acid.
REFERENCES:
patent: 3468849 (1969-09-01), Rothert
patent: 4057534 (1977-11-01), Konishi et al.
E. I. Du Pont de Nemours and Company
Phynes Lucille M.
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