Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing
Patent
1985-11-22
1986-09-02
Shaver, Paul F.
Organic compounds -- part of the class 532-570 series
Organic compounds
Silicon containing
C07F 710
Patent
active
046097490
ABSTRACT:
Carboxylic acid trimethylsilyl esters (I) and trimethylsilyl carboxylic acid amides can be prepared simultaneously from the corresponding carboxylic acid anhydrides; the esters (I) and monocarboxylic acid trimethylsilyl amides are formed first and can then be recovered, or else the bis-trimethylsilyl carboxylic acid amides are formed by further transposition with trimethylchlorosilane in the presence of tertiary amines, and are separated from the carboxylic acid trimethylsilyl ester (I) and recovered.
REFERENCES:
patent: 3839387 (1974-10-01), Chow et al.
patent: 4059559 (1977-11-01), Burkhardt et al.
Kotzsch Hans-Joachim
Vahlensieck Hans-Joachim
Dynamit Nobel AG
Shaver Paul F.
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