Method for the simultaneous preparation of carboxylic acid trime

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

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C07F 710

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046097490

ABSTRACT:
Carboxylic acid trimethylsilyl esters (I) and trimethylsilyl carboxylic acid amides can be prepared simultaneously from the corresponding carboxylic acid anhydrides; the esters (I) and monocarboxylic acid trimethylsilyl amides are formed first and can then be recovered, or else the bis-trimethylsilyl carboxylic acid amides are formed by further transposition with trimethylchlorosilane in the presence of tertiary amines, and are separated from the carboxylic acid trimethylsilyl ester (I) and recovered.

REFERENCES:
patent: 3839387 (1974-10-01), Chow et al.
patent: 4059559 (1977-11-01), Burkhardt et al.

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