Production of hydroperoxides from olefins

Details Production of hydroperoxides from olefins Production of hydroperoxides from olefins

1973-08-27

1979-05-15

Thomas, Jr., James O.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

C07C17902

Patent

active

041547683

ABSTRACT:
Increase in yields of alkyl hydroperoxides from corresponding olefins by reacting the olefin with an inorganic peroxide in the presence of an acid catalyst, the acid concentration being adjusted to an optimum range which is generally about 15-30% by total weight of the reactive ingredients. Where the olefin contains over 7 carbon atoms, peroxide-compatible surfactants are included in the reaction mixture and the yield of hydroperoxide is further improved.

REFERENCES:
patent: 2223807 (1940-12-01), Milas
patent: 3308163 (1967-03-01), McKellin
McCutcheon, "Synthetic Detergents", (1950), p. 273.
Davis et al., "Nature", (1952), vol. 170, No. 4329, p. 668.
Davis et al., "J. Chem. Soc., London", (1953), pp. 1541-1547.

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