Preparation of .alpha.-substituted acrylamides

Details Preparation of .alpha.-substituted acrylamides Preparation of .alpha.-substituted acrylamides

1984-12-03

1986-07-01

Warren, Charles F.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

564123, 564204, C11C 300, C07C10210

Patent

active

045979073

ABSTRACT:
.alpha.-substituted acrylamides of the general formula I ##STR1## where R.sup.1 is a straight-chain, branched or cyclic alkyl radical of not more than 15 carbon atoms which can be unsubstituted or further substituted, are prepared by a process in which the corresponding .alpha.-substituted acrolein oximes are heated at from 40.degree. to 250.degree. C. in the presence of a copper(II) carboxylate.

REFERENCES:
patent: 3105741 (1963-10-01), Moore, Jr.
patent: 4365092 (1982-12-01), Harwell et al.
J. Am. Chem. Soc. 83, (1961), 1983.
Rec. Trav. Chim. Pays Bas 95, (1976) 123.

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