Brass alloys

Metal treatment – Stock – Copper base

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148434, 420471, 420472, 420473, 420474, 420475, 420476, 420479, C22C 902

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056538278

ABSTRACT:
Reduced-lead yellow brass alloys are disclosed. The alloys comprise copper; zinc; an amount of bismuth effective to enhance castability of the alloys; and an amount of selenium effective to increase machinability of the alloy. Preferably, the alloys further include an amount of antimony effective to inhibit dezincification of the alloys. In a particularly preferred embodiment, an alloy according to the present invention comprises zinc; copper in an amount ranging from about 62.5% to about 64.0% by weight; tin in an amount ranging from about 0.2% to about 0.4% by weight; iron in an amount ranging from about 0.1% to about 0.3% by weight; nickel in an amount ranging from about 0.15% to about 0.25% by weight; aluminum in an amount ranging from about 0.3% to about 0.6% by weight; bismuth in an amount ranging from about 0.8% to about 1.0% by weight; antimony in an amount ranging from about 0.02% to about 0.04% by weight; and selenium in an amount ranging from about 0.05% to about 0.25% by weight. The disclosed alloys exhibit excellent castability, machinability, and polishability, and, when used in decorative plumbing fixtures, will not dezincify nor leach lead into potable water.

REFERENCES:
patent: 1149850 (1915-08-01), Metzger
patent: 1921417 (1933-08-01), Leach
patent: 1959509 (1934-05-01), Tour
patent: 2026209 (1935-12-01), Brace
patent: 2073371 (1937-07-01), Hensel
patent: 2188681 (1940-01-01), Freeman et al.
patent: 2246328 (1941-06-01), Smith
patent: 2330062 (1943-09-01), Lempert
patent: 2581903 (1952-10-01), Bailey et al.
patent: 2975255 (1961-03-01), Lafferty
patent: 3246979 (1966-04-01), Lafferty
patent: 3370942 (1968-02-01), Inoue
patent: 3395986 (1968-08-01), Gruber
patent: 3437479 (1969-04-01), Nakajima
patent: 3502465 (1970-03-01), Nakajima
patent: 3551214 (1970-12-01), Ford et al.
patent: 3725052 (1973-04-01), Masumoto et al.
patent: 3770497 (1973-11-01), Hassler et al.
patent: 3805000 (1974-04-01), Roy
patent: 4009027 (1977-02-01), Naidich et al.
patent: 4091248 (1978-05-01), Arakawa et al.
patent: 4180398 (1979-12-01), Parikh
patent: 4198232 (1980-04-01), Parr et al.
patent: 4231814 (1980-11-01), Watanabe et al.
patent: 4464213 (1984-08-01), Nielsen
patent: 4499009 (1985-02-01), Yamanaka et al.
patent: 4511410 (1985-04-01), Shapiro et al.
patent: 4517033 (1985-05-01), Okumura et al.
patent: 4537743 (1985-08-01), Yamanaka et al.
patent: 4551395 (1985-11-01), Lloyd
patent: 4586967 (1986-05-01), Shapiro et al.
patent: 4677264 (1987-06-01), Okumura et al.
patent: 4678720 (1987-07-01), Hsu et al.
patent: 4708739 (1987-11-01), Kellie et al.
patent: 4733018 (1988-03-01), Prabhu et al.
patent: 4786469 (1988-11-01), Weber et al.
patent: 4853184 (1989-08-01), Naya et al.
patent: 4865805 (1989-09-01), Holowaty
patent: 4879094 (1989-11-01), Rushton
patent: 5000779 (1991-03-01), German et al.
patent: 5017250 (1991-05-01), Ashok
patent: 5039478 (1991-08-01), Sankaranarayanan
patent: 5098487 (1992-03-01), Brauer et al.
patent: 5102748 (1992-04-01), Wylam et al.
patent: 5137685 (1992-08-01), McDevitt et al.
patent: 5147469 (1992-09-01), Kanzaki et al.
patent: 5167726 (1992-12-01), LoIacono et al.
patent: 5174469 (1992-12-01), Policapelli
patent: 5198154 (1993-03-01), Yokoyama et al.
patent: 5288458 (1994-02-01), McDevitt et al.
patent: 5330712 (1994-07-01), Singh
patent: 5360591 (1994-11-01), Ruetz et al.
H.C.H. Carpenter, "The Critical Point at 470.degree. C. In Copper-Zinc Alloys", The University, Manchester, pp. 70-104. (1912).
D.W. Davies, "Bismuth In Copper and Copper Base Alloys: A Literature Review", Copper Development Assoc., Inc., Aug. 1993.
CA958):66285q. Distribution of lead and bismuth in the structure of cast copper and copper alloys. Pikunov et al., (Mosk. Ins. STali Splavov, Moscow, USSR). Izv. Vyssh. Uchebn. Zaved., Tsvetn. Metall. (2), 80-4 (Russ) 1981. Coden: Ivutak. ISSN: 0021-3438.
S.2637, 101st Congress, 2d Session, A Bill, May 16 (legislative day, Apr. 18), 1990, Mr. Reid et al., pp. 1-35.
Angino et al., "Drinking Water Quality and Chronic Disease," Environmental Science & Technology, vol. 11, No. 7, (Jul. 1977) pp. 661-665.
Audy, J. et al., "Composition and Microstructure of Medieval Bells," Prakt. Metallogr, 29 (2), (1992) pp. 74-85.
Bishop, "Lead-Free Copper Alloys For Plumbing Developed by AT&T's Bell Laboratories," The Wall Street Journal, (May 15, 1991).
Blazey, Clement, "Brittleness in Copper," The Journal of the Institute of Metals, vol. XLVI, (1931) pp. 353-383.
CA Selects: Bismuth Chemistry, Issue 20, (1992) p. 1.
Carpenter, "The Effect of Other Metals on the Structure of the beta Constituent in Copper-Zinc Alloys," The Journal of the Institute of Metals, vol. VIII, No. 2, (1912) pp. 59-85.
Chemical Abstracts 106: 37311c, vol. 106, (1987) p. 270.
Chemical Abstracts 91: 95313v, vol. 91, (1979) p. 95317.
Cibula, A., "Grain-Refining Additions for Cast Copper Alloys," The Journal of the Institute of Metals, vol. 82, (Jan. 21, 1954) pp. 513-524.
Cibula, A., "Influence of Grain Size on the Structure, Pressure-tightness and Tensile Properties of Sand-cast Bronzes and Gunmetals," The British Non-Ferrous Metals Research Association, Paper No. 1211, pp. A73-A90.
Copper Development Association, "Alloy Data--Part 2," Standards Handbook, (1985).
"Corrosion of Metals and Alloy--Determination of Dezincification Resistance of Brass," International Organization for Standardization ISO 6509, First Edition--(1981) 07-01.
Dennison, J.P., "The Application of Grain Refinement to Cast Coper-Aluminum Alloys Containing the Beta Phase," The Journal of the Institute of Metals, vol. 81, (Dec. 12, 1952) pp. 513-520.
Dennison, J.P., "The Refinement of Cast Grain-Size in Copper-Aluminum Alloys Containing 7-9 Per Cent. Aluminum," The Journal of the Institute of Metals, vol. 85, (Feb. 20, 1956) pp. 8-10.
Dresher, W.H., "Lead-free and reduced-lead copper-base cast plumbing alloys," Metall, 47 Jahrgang, Heft 1, (Jan. 1993) pp. 26-33.
Carpenter, "Further Experiments on the Critical Point at 470.degree.. In Copper-Zinc Alloys, " Read at Annual General Meeting, London, Jan. 17, 1912.
Eborall, "Some Observations of the Mode of Occurrence of Selenium, Tellurium and Bismuth in Copper," The Journal of the Institute of Metals, vol. LXX, (1944) pp. 435-446.
Feder, "A New Form of Brass, to Cut Lead in Drinking Water," The New York Times, (May 15, 1991), p. D7.
Flemings, M.C., "Solidification Processing," McGraw-Hill, Inc., (1974) pp. 252-258.
Foundry, "Technical Developments," Management & Technology, (Oct. 1993) p. 20.
Gordon et al., "Bismuth Bronze From Machu Picchu, Peru," Science, vol. 223, (Feb. 10, 1984) p. 585.
Jackson et al., "A Preliminary Assessment of the Value of Minor Alloy Additions in Counteracting the Harmful Effect of Impurities on the Hot Workability of Some Copper Alloys," The Journal of the Institute of Metals, vol 98, (1970) pp. 193-198.
News Release--"New Family of Lead-Free Red Brass Cast Alloys Announced," Copper Development Association, Inc., (Aug. 2, 1994) pp. 1-6.
Northcott, L., "The Influence of Alloying Elements on the Crystalization of Copper. Part II-Large Additions and the Part Played by the Constitution," The Journal of the Institute of Metals, vol. LXV, (Nov. 22, 1938) pp. 173-204.
Northcott, L., "The Influence of Alloying Elements on the Crystallization of Copper. Part I-Small Additions and the Effect of Atomic Structure," The Journal of the Institute of Metals, vol. LXII, (Oct. 01, 1937) pp. 101-136.
Ojebuoboh, F.K., "Bismuth-Production, Properties, and Applications," JOM, (Apr. 1992) pp. 46-49.
Oya et al., Rept. Casting Res. Lab, Waseda University, No. 30, 1979, p. 93-100.
Plewes, J.T. et al., "Free-Cutting Copper Alloys Contain No Lead," Advanced Materials and Processes, (Oct. 1991) pp. 23-27.
Plewes et al., "Bismuth as an Additive in Free-Machining Brasses," Modern Casting, (Feb. 1993) pp. 32-33.
Press Release, Copper Development Association. USP 1149850 Aug. 10, 1915.
Price et al., "Bismuth-Its Effect on the Hot-Working and Cold-Working Properties of Alpha and Alpha-Beta Brasses," Transactions of A.I.M.E., (1942) pp. 136-143.
Samuels, "The Metallography

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