Process for producing carboxylic acid alkylester after products

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C11C 302

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044216920

ABSTRACT:
A method for preparing carboxylic acid alkylester after products free of nitrogen containing compounds. These after products, free of nitrogen containing compounds, are prepared by:
(1) reacting olefins with carbon monoxide and alkanols in the presence of a catalyst system consisting of a cobalt compound and pyridine, non-orthosubstituted alkylpyridines or a mixture of these pyridines at elevated pressures and elevated temperatures to produce carboxylic acid alkylesters containing nitrogenated compounds resulting from the pyridines;
(2) hydrogenating the carboxylic acid alkylesters to produce after products which include alcohols; and
(3) treating the after products with acid ion exchangers to remove the nitrogenated compounds.

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