Chemistry of carbon compounds – Miscellaneous organic carbon compounds
Patent
1980-03-19
1981-12-29
Welsh, Maurice J.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
260 37R, 260 37N, 260 38, 525135, 525150, 528148, 528149, 528153, 528154, 528155, 528156, 528158, C08G 1404
Patent
active
043081800
ABSTRACT:
A rubber composition comprising vulcanizable natural or synthetic rubber and a sulfide resin produced by (1) reacting a component (A) with a componet (B), followed by reacting with a component (D), or (2) reacting a component (A) with a component (B), followed by reacting with a component (C) and a component (D) simultaneously or sequentially, and if desired reacting the resulting phenol resin with an acylating agent, the component (A) being a phenol compound of the following formula, and/or an acylated compound thereof, ##STR1## wherein R.sub.1 and R.sub.2 are each a hydrogen atom, a hydroxyl, carboxyl, amino, C.sub.1 -C.sub.18 alkyl, C.sub.3 -C.sub.10 cycloalkyl, C.sub.3 -C.sub.10 cycloalkenyl or C.sub.7 -C.sub.12 aralkyl group or a phenyl group unsubstituted or substituted with at least one C.sub.1 -C.sub.3 alkyl group, the component (B) being a sulfur chloride or sulfur, the component (C) being an aldehyde, and the component (D) being at lest one hydroxyaryl compound of the following formula, and/or an acylated compound thereof, ##STR2## wherein R.sub.3 is a --OR.sub.6,--NHR.sub.6, --COOR.sub.6, --OCOR.sub.6, phenyl group unsubstituted or substituted with at least one C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.18 alkyl, C.sub.3 -C.sub.10 cycloalkyl, C.sub.3 -C.sub.10 cycloalkenyl or C.sub.7 -C.sub.12 aralkyl group, and R.sub.4 and R.sub.5 are each a hydrogen atom, --OR.sub.6, --NHR.sub.6,--COOR.sub.6, --0COR.sub.6, phenyl group unsubstituted or substituted with at least one C.sub.1-C.sub.3 alkyl, C.sub.1 -C.sub.18 alkyl, C.sub.3 -C.sub.10 cycloalkyl, C.sub.3 -C.sub.10 cycloalkenyl or C.sub.7 -C.sub.12 aralkyl group in which R.sub.6 is a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group.
REFERENCES:
patent: 2445736 (1948-07-01), Gottschalk et al.
patent: 3455851 (1969-07-01), Meredith et al.
Ishii Tamaki
Okamura Haruki
Yamaguchi Tetsuo
Sumitomo Chemical Company Limited
Welsh Maurice J.
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