Optically active alcohols

Details Optically active alcohols Optically active alcohols

1989-11-17

1991-08-20

Waddell, Frederick E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

549550, 549208, C07F 702

Patent

active

050415590

ABSTRACT:
Provided herein is an optically active alcohol having a silyl group, stannyl group, or halogen atom at the .gamma.-position, selected from compounds represented by the general formula [I], ##STR1## the general formula [II], ##STR2## the general formula [III], ##STR3## and the general formula [IV], ##STR4## (where, R denotes a C.sub.1 -C.sub.10 substituted or unsubstituted alkyl group or substituted or unsubstituted phenyl group; A denotes a silyl group represented by ##STR5## a stannyl group represented by ##STR6## or a halogen atom. R.sup.1, R.sup.2, and R.sup.3 are substituted or unsubstituted C.sub.1 -C.sub.10 alkyl groups or substituted or unsubstituted phenyl group, which may be the same or different, provided that this does not apply in the case where A represents a stannyl group or halogen atom in the general formulas [III] and [IV].); a process for producing the same, and a process for resolving the optically active alcohol into isomers of high optical purity.

REFERENCES:
Tetrahedron Letters, vol. 28, No. 18, pp. 2033-2036, 1987 (Okamoto et al.)
Bulletin of the Chemical Society of Japan, vol. 52(9), pp. 2646-2652 (1979) M. Obayashi et al.
Tetrahedron Letters, vol. 23, No. 52, pp. 5579-5582, Pergamon Press Ltd., GB; A. S. Narula.
Tetrahedron Letters, vol. 24, No. 48, pp. 5421-5424, 1983, Pergamon Press Ltd., Oxford, GB, A. Narula.
Chemical Communications, Journal of the Chemical Society, No. 17, Sep. 1, 1986, pp. 1323-1325, Y. Kitano et al.
Tetrahedron Letters, vol. 28, No. 18, pp. 2041-2044, 1987, Pergamon Journals Ltd., GB; A. T. Russell et al.

Affiliated with

Also associated with

Rating

Optically active alcohols does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Optically active alcohols, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Optically active alcohols will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-1009056