Processes for preparing cyclohexadiene derivatives

Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy

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260396N, 568377, B01J 110, C07C 4500

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active

042016398

ABSTRACT:
Described is a process for preparing cyclohexadiene derivatives having the generic formula: ##STR1## wherein R is one of C.sub.1 -C.sub.5 alkyl, R.sub.1 is methyl when R.sub.2 is hydrogen comprising the step of reacting a 1-alkyl-3,5,5-trimethylcyclohexa-1,3-diene or a 1-alkyl-3,4,4-trimethylcyclohexa-1,3-diene with oxygen in the presence of light, an ultraviolet sensitizer, and a basic catalyst; and fractionally distilling the resulting product.

REFERENCES:
patent: 4032547 (1977-06-01), Bacha et al.
Cook et al., I, "CA" 78:71107m (1973).
Bardyshev et al., "CA" 75:20647t (1971).
Cook et al., II, "CA" 78:97164c (1973).
Koch et al., "Tetrahedron", 1968, 24(21), 6295-6318 ("CA"70:2997z , 1969).

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