Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing
Reexamination Certificate
2006-09-12
2011-10-25
Lu, Caixia (Department: 1765)
Organic compounds -- part of the class 532-570 series
Organic compounds
Heavy metal containing
C556S007000, C556S032000, C526S134000, C526S160000, C526S164000, C526S171000, C526S172000, C502S152000, C502S155000
Reexamination Certificate
active
08044225
ABSTRACT:
A zwitterionic Group VIII transition metal complex containing the simple and relatively small 3-(arylimino)-but-1-en-2-olato ligand that catalyzes the formation of polypropylene and high molecular weight polyethylene. A novel feature of this catalyst is that the active species is stabilized by a chelated olefin adduct. The present invention also provides methods of polymerizing olefin monomers using zwitterionic catalysts, particularly polypropylene and high molecular weight polyethylene.
REFERENCES:
patent: 7776943 (2010-08-01), Scott et al.
Ittel, S. D.; Johnson, L. K.; Brookhart, M.Chem. Rev.2000, 100, 1169-1203.
Gibson, V. C.; Spitzmesser, S. K.Chem. Rev.2003, 103, 283-315.
Johnson, L. K.; Killian, C. M.; Brookhart, M.J. Am. Chem. Soc.1995, 117, 6414-6415.
Klabunde, U.; Ittel, S. D.J. Mol. Catal.1987, 41, 123-124.
Ostoja-Starzewski, K. A.; Witte, J.; Reichert, K. H.; Vasiliou, G. InTransition Metals and Organometallics as Catalysts for Olefin Polymerization; Kaminsky, W., Sinn, H., Eds.; Springer: Berlin, 1998; p. 349.
Younkin, T. R.; Connor. E. F.; Henderson, J. I.; Friedrich, S. K.; Grubbs, R. H.; Bansleben, D. A.Science2000, 287, 460-462.
Jenkins, J. C.; Brookhart, M.J. Am. Chem. Soc.2004, 126, 5827-5842.
Strauch, J. W.; Erker, G.; Kehr, G.; Fröhlich, R.Angew. Chem. Int. Ed. Engl.2002, 41, 2543-2546 Bazan, G. C.; Rodriguez, G.; Ashe III, A. J.; Al-Ahmad, S.; Müller, C.J. Am. Chem. Soc.1996, 118, 2291-2292.
Barnhart, R. W.; Bazan, G. C.; Mourey, T.J. Am. Chem. Soc.1998, 120, 1082-1083.
Komon, Z. J. A.; Diamond, G. M.; Leclerc, M. K.; Murphy, V.; Okazaki, M.; Bazan, G. C.J. Am. Chem. Soc.2002, 122, 15280-15285.
Wasilke, J. C.; Obrey, S. J.; Baker, R. T.; Bazan, G. C.Chem. Rev.2005, 105, 1001-1020.
Bonnet, M. C.; Dahan, F.; Ecke, A.; Keim, W.; Schultz, R. P.; Tkatchenko, I.J. Chem. Soc., Chem. Commun. 1994, 615-616.
Komon, Z. J. A.; Bu, X.; Bazan, G. C.J. Am. Chem. Soc. 2000, 122, 1830-1831.
Komon, Z. J. A.; Bu, X.; Bazan, G. C.J. Am. Chem. Soc. 2000, 122, 12379-12380.
Deng, L. Q.; Margl, P.; Ziegler, T.J. Am. Chem. Soc. 1997, 119, 1094-1100.
Lee, B. Y.; Bazan, G. C.; Vela, J.; Komon, Z. J. A.; Bu, X.J. Am. Chem. Soc. 2001, 123, 5352-5353.
Chen, Y.; Wu, G.; Bazan, G. C.Angew, Chem., Int. Ed. Engl. 2005, 44, 1108-1112.
Kwon, H. Y.; Lee, S. Y.; Lee, B. Y.; Shin, D. M.; Chung, Y. K.Dalton Transactions2004, 921-928.
Shim, C. B; Kim, Y. H.; Lee, B. Y.; Shin, D. M.; Chung, Y. K.J. Organomet. Chem. 2003, 675, 72-76.
Kim, Y. H.; Kim, T. H.; Lee, B. Y.; Woodmansee, D.; Bu, X.; Bazan, G. C.Organometallics2002, 21, 3082-3084.
Shim, C. B.; Kim, Y. H.; Lee, B. Y.; Dong, Y.; Yun. H.Organometallics2003, 22, 4272-4280.
Lee, B. Y.; Bu, X., Bazan, G. C.Organometallics2001, 20, 5425-5431.
Schmid, M.; Eberhardt, R.; Kukral, J.; Rieger, B.Z. Naturfosch. B2002, 57, 1141-1146.
Carmona, E.; Paneque, M.; Poveda, M. LPolyhedron1989, 8, 285-291.
Pappalardo, D.; Mazzeo, M.; Antinucci, S.; Pellecchia, C.Macromolecules2000, 33, 9483-9487.
Ewen, J. A.J. Am. Chem. Soc. 1984, 106, 6355-6364.
Bazan Guillermo C.
Chen Yaofeng
Berliner & Associates
Lu Caixia
The Regents of the University of California
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