ZrO 2 -Al 2 O 3 composite ceramic material and production...

Compositions: ceramic – Ceramic compositions – Refractory

Reexamination Certificate

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Reexamination Certificate

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07928028

ABSTRACT:
A ZrO2—Al2O3composite ceramic material having excellent wear resistance, hardness, strength and toughness is provided. This ceramic material comprises a ZrO2phase composed of 90 vol % or more of tetragonal ZrO2, and containing 10 to 12 mol % of CeO2as a stabilizer, and an Al2O3phase. An amount of the Al2O3phase in the ceramic material is in a range of 20 to 70 vol %, and preferably 40 to 70 vol %. In the composite ceramic material, Al2O3grains each having a fine ZrO2grain therein are dispersed. Some of the Al2O3grains each having the fine ZrO2grain therein are trapped within ZrO2grains to form composite grains. A ratio of the number of the Al2O3grains each having the fine ZrO2grain therein relative to the number of the entire Al2O3grains dispersed in the composite ceramic material is 10% or more, and preferably 50% or more.

REFERENCES:
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European Search Report mailed on Jun. 15, 2005.
Masahiro Nawa, et al., “The Effect of TiO2Addition on Strengthening and Toughening in Intragranular Type of 12Ce-TZP/Al2O3Nanocomposites”, Journal of the European Ceramic Society, Elsevier Science Publishers, Barking, Essex, GB, vol. 18, No. 3, 1998, pp. 209-219, XP004101497, ISSN: 0955-2219.
Examination Report dated Apr. 7, 2006 with English Translation.
Notification of Reasons for Refusal for the Application No. 2005-082516 from Japan Patent Office mailed Jun. 23, 2009.

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