ZR/V multi-site olefin polymerization catalyst

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

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502114, 502115, 502132, 502133, 526116, 526121, 526128, B01J 3100

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active

053995406

ABSTRACT:
A catalyst useful in the polymerization of olefins, especially ethylene, is disclosed. The catalyst is obtained by admixing a zinc composition, a zirconium composition and a vanadium composition. The catalyst may be combined with a co-catalyst and, optionally, a modifier to yield an olefin polymerization system. The catalyst exhibits extremely high activity, good hydrogen response and produces polymers having broad molecular weight distribution ("MWD") and manifesting bimodal MWD profile.

REFERENCES:
patent: 2919265 (1959-12-01), Brooks
patent: 3029231 (1962-04-01), van Amerongen
patent: 3030350 (1962-04-01), de Jong et al.
patent: 3051690 (1962-08-01), Vandenberg
patent: 3058963 (1962-10-01), Vandenberg
patent: 3144473 (1964-08-01), Boor, Jr. et al.
patent: 3168484 (1965-02-01), Engel et al.
patent: 3218266 (1965-11-01), Ludlum
patent: 3231515 (1966-01-01), Ziegler et al.
patent: 3240773 (1966-03-01), Boor, Jr.
patent: 3260708 (1966-07-01), Natta et al.
patent: 3345351 (1967-10-01), McCall et al.
patent: 3371079 (1968-02-01), Peters et al.
patent: 3392162 (1968-07-01), Ziegler et al.
patent: 3394118 (1968-07-01), Boor, Jr.
patent: 3457244 (1969-07-01), Fukuda et al.
patent: 3535269 (1970-10-01), Tanaka et al.
patent: 3655583 (1972-04-01), Yamamoto et al.
patent: 3786032 (1974-01-01), Jennings et al.
patent: 3899477 (1975-08-01), Altemore et al.
patent: 4008358 (1977-02-01), Abe et al.
patent: 4063009 (1977-12-01), Ziegler et al.
patent: 4109071 (1978-08-01), Berger et al.
patent: 4154701 (1979-05-01), Melquist
patent: 4192772 (1980-03-01), Berger et al.
patent: 4202958 (1980-05-01), Yamaguchi et al.
patent: 4256865 (1981-03-01), Hyde et al.
patent: 4381253 (1983-04-01), Shipley
patent: 4383119 (1983-05-01), Pullukat et al.
patent: 4397761 (1983-08-01), McDaniel et al.
patent: 4426317 (1984-01-01), Rogers
patent: 4434242 (1984-02-01), Roling et al.
patent: 4435518 (1984-03-01), Pennington et al.
patent: 4435519 (1984-03-01), Veazey et al.
patent: 4435520 (1984-03-01), Aylward
patent: 4508842 (1985-04-01), Beran et al.
patent: 4513095 (1985-04-01), Speca
patent: 4536487 (1985-08-01), Speca
patent: 4559318 (1985-12-01), Smith et al.
patent: 4610974 (1986-09-01), Speca
patent: 4611038 (1986-09-01), Brun et al.
patent: 4663404 (1987-05-01), Invernizzi et al.
patent: 4710552 (1987-12-01), Bachl et al.
patent: 4754007 (1988-06-01), Pullukat et al.
patent: 4810761 (1989-03-01), Zoeckler et al.
patent: 4812432 (1989-03-01), Zoeckler et al.
patent: 4831090 (1989-05-01), Bachl et al.
patent: 4866021 (1989-09-01), Miro et al.
patent: 4918038 (1990-04-01), Samuels et al.
patent: 5079205 (1992-01-01), Canich
patent: 5143882 (1992-09-01), Bueschges et al.
patent: 5155079 (1992-10-01), Cribbs et al.
Karol, et al. (1988) "Developments with High-Activity Titanium, Vanadium, and Chromium Catalysts in Ethylene Polymerization" Kaminsky and Sinn (Eds), 141-161.
Smith, et al. (1985) "Bimetallic Halides, Crystal Structure of an Ethylene Polymerization by VCl.sub.2.ZnCl.sub.2.4THF" Inorg. Chem. 24, 2997-3002.
Karol, et al. (1987) "Ethylene Polymerization with High Activity Titanium, Vanadium and Chromium Catalysts" Book of Abstracts, 193rd ACS National Meeting, Denver, Colo., Apr. 5-10, 1987.

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