Zirconium urethane catalysts

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From reactant having at least one -n=c=x group as well as...

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521124, C08G 1822

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active

059656867

ABSTRACT:
The present invention is directed to novel metal organocomplexes as catalysts for the reaction of compounds with isocyanate and hydroxy functional groups to form urethane and/or polyurethane and the process employing such catalysts. More particularly, the present invention is directed to novel complexes of zirconium or hafnium with diketones or alkylacetoacetoates. These novel catalysts are useful for the production of urethanes and polyurethanes which are important in many industrial applications, such as: coatings, foams, adhesives, sealants, and reaction injection molding (RIM) plastics.

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Proceedings of Water Borne and High Solids Coatings Symposium, Feb. 25-27, 1987, New Orleans, at p. 460.
B.D. Nahlovsky and G.A. Zimmerman, Int. Jahrestag. Fraunhofer -Inst. Treib-Explosivst., 18th (Technol. Energ. Mater.), 39:1-12, 1987.
R.C. Fay in the Chapter on Zirconium and Hafnium, in Geoffrey Wikinson ed., Comprehensive Coordination Chemistry, vol. 3, p. 363, Pergamon Press, (1987).
Organic Coatings Science Technology, vol. 1, Wiley-Interscience Co., 1992, pp. 182-211.

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