Zirconium and hafnium tetrachloride separation by extractive dis

Distillation: processes – separatory – Adding material to distilland except water or steam per se – At least two materials

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203 84, 423 73, 423 76, 423492, B01D 340, C01G 2504, C01G 2704

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active

047494484

ABSTRACT:
This is a molten salt extractive distillation process for separating hafnium from zirconium. It utilizes at least principally a ZnCl.sub.2 --Ca/MgCl.sub.2 molten salt solvent, and preferably ZnCl.sub.2 --Ca/MgCl.sub.2 in a near 95-15 mixture. The extraction column is preferably run about 380.degree.-420.degree. C. at about one atmosphere and stripping is preferably done at about 385.degree.-450.degree. C. utilizing an inert gas carrier.

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