Zinc/nickel/phosphorus coatings and elecroless coating method th

Coating processes – Immersion or partial immersion – Metal base

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427304, 427305, 427438, 4274431, C23C 2600

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053044037

ABSTRACT:
In a preferred method, a zinc-rich alloy coating is applied to a substrate using an electrolysis deposition solution which contains a metal salt of zinc and a metal salt of nickel each in an amount sufficient to provide a weight ratio of zinc to nickel (Zn:Ni) of at least about 1:1; a phosphorus-containing reducing agent in an amount sufficient to cause reduction of the zinc and the nickel to ions thereof; sufficient complexing agent to maintain the nickel ions and the zinc ions in solution; and a buffer in an amount sufficient to achieve a desired pH. Preferably, the surface of the substrate is pretreated or precatalyzed before deposition by a sensitizing step using tin and an activating step using palladium.

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Konrad Parker, Electroless Nickel: State of the Art, Mar. 1992.
Abstracts from 1991 American Chemical Society database for German Pat. No. 2747001 and Japanese Patent Nos. 57-12592 and 62-274076.

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