Zinc electrode and rechargeable zinc-air battery

Chemistry: electrical current producing apparatus – product – and – With pressure equalizing means for liquid immersion operation

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429 27, 429105, 296231, H01M 806

Patent

active

048429635

ABSTRACT:
An improved zinc electrode is disclosed for a rechargeable zinc-air battery comprising an outer frame and a porous foam electrode support within the frame which is treated prior to the deposition of zinc thereon to inhibit the formation of zinc dendrites on the external surface thereof. The outer frame is provided with passageways for circulating an alkaline electrolyte through the treated zinc-coated porous foam. A novel rechargeable zinc-air battery system is also disclosed which utilizes the improved zinc electrode and further includes an alkaline electrolyte within said battery circulating through the passageways in the zinc electrode and an external electrolyte circulation means which has an electrolyte reservoir external to the battery case including filter means to filter solids out of the electrolyte as it circulates to the external reservoir and pump means for recirculating electrolyte from the external reservoir to the zinc electrode.

REFERENCES:
patent: 4115626 (1978-09-01), Sauer et al.
patent: 4328287 (1982-05-01), Sammells et al.
patent: 4517258 (1985-05-01), Bromoel
patent: 4551399 (1985-11-01), Despic
Foller, Improved Slurry Zinc/Air Systems as Batteries for Urban Vehicle Propulsion, Journal of Applied Electrochem, vol. 16, (1986), pp. 527-543.
Iacovangelo et al., Parametric Study of Zinc Deposition on Porous Carbon in a Flowing Electrolyte Cell, Journal of the Electrochemical Society, vol. 132 (1985), p. 851.
Will et al., An X-Ray Radiography-Densitometry Technique for Quantitative Determination of Metal Deposit Profiles, Journal of the Electrochemical Soc., vol. 131, No. 3, Mar. 1984, pp. 590-595.

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