Zeolite modification and its use in conversion of alcohols and e

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By ring formation from nonring moiety – e.g. – aromatization,...

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585415, 585467, 585469, 585470, 585475, 585481, 585640, 585654, 585733, 208116, 208120, C07C 120

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active

046652485

ABSTRACT:
The ion-exchange capacity and acid catalytic activity of a ZSM-5 type zeolite are increased by treatment of a physical mixture of the zeolite and an inorganic oxide with water in the presence of an alkali metal cation.
Specifically, the catalyst is prepared by contacting a mixture of a crystalline zeolite having a silica to alumina ratio above 12 and a Constraint Index between about 1 and about 12, and a solid source of aluminum with liquid water in the presence of an activating amount of an alkali metal cation and under a combination of conditions including a temperature up to about 370.degree. C. for less than about an hour to about 100 hours to induce increased activity to the zeolite.

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