Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs – And additional al or si containing component
Patent
1994-09-15
1996-11-05
Caldarola, Glenn A.
Catalyst, solid sorbent, or support therefor: product or process
Zeolite or clay, including gallium analogs
And additional al or si containing component
502 71, 502 85, B01J 2926, B01J 2940
Patent
active
055717683
ABSTRACT:
There is provided a zeolite, such as ZSM-5, which is functionalized with at least one organosiliceous group of the formula, SiR.sub.n (OX).sub.4-n, where R is at least one hydrocarbyl group, n is 1 or 2 and X is Si or H. There is also provided a method for functionalizing a zeolite by treatment with a silicone compound, such as hexamethyldisiloxane, under vapor phase conditions. This contacting may take place in the presence of hydrogen and an organic carrier. The functionalized zeolites may provide a catalyst which is both highly active and highly selective for converting aromatic hydrocarbons, especially alkylbenzene compounds, to products comprising the para-isomer of dialkylbenzenes. The disproportionation of toluene is an example of such a reaction.
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Chang Clarence D.
Rodewald Paul G.
Bleeker R. A.
Caldarola Glenn A.
Mobil Oil Corporation
Roberts P. W.
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