Chemistry of inorganic compounds – Zeolite – Organic compound used to form zeolite
Patent
1994-09-14
1996-04-30
Bell, Mark L.
Chemistry of inorganic compounds
Zeolite
Organic compound used to form zeolite
423706, 423718, 423713, 502 62, 502 77, 208 46, 585400, 585407, C01B 3904, C01B 3912, C01B 3946, C01B 3948
Patent
active
055122671
ABSTRACT:
A zeolite composition CIT-1 is provided, the composition having a mole ratio greater than about 20:1 of a first oxide selected from silicon oxide, germanium oxide, or mixtures thereof to a second oxide comprising boron oxide; which zeolite composition has a specific X-ray powder diffraction pattern in accordance with Table 1 of the disclosure. In one embodiment, the second oxide may comprise mixtures of boron oxide with one or more of aluminum oxide, gallium oxide, iron oxide, titanium oxide and vanadium oxide. Also disclosed is a method for making CIT-1 zeolites comprising the preparation of an aqueous mixture containing sources of a N,N,N-trimethyl cis-myrtanyl ammonium ion, boron oxide or mixtures of boron oxide with one or more of aluminum oxide, gallium oxide, iron oxide, titanium oxide and vanadium oxide, and an oxide selected from silicon oxide, germanium oxide, and mixtures thereof. The mixture is maintained under sufficient crystallization conditions, preferably at a temperature of at least 100.degree. C., in an autoclave and under autogenous pressure until the crystals of the zeolite are formed.
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Davis Mark E.
Lobo Raul F.
Bell Mark L.
California Institute of Technology
Sample David
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