Yttrium oxide-aluminum oxide composite particles and method for

Stock material or miscellaneous articles – Coated or structually defined flake – particle – cell – strand,... – Particulate matter

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428404, 4284111, 428688, 428701, B32B 1502, B32B 1702, B32B 1900, B32B 2102

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060804858

ABSTRACT:
Provided by the invention is a powder of alumina-yttria composite particles of which each particle has a structure consisting of a core of alumina and cladding layer of yttria. By virtue of the microscopically intimate and uniform mixing condition of the two oxide components, the powder is useful as a base material of sintered ceramic bodies or as an ingredient in a protective film on fluorescent lamps. The composite particles are prepared by a process comprising the steps of: suspending alumina particles in an aqueous solution containing a water-soluble yttrium salt such as nitrate; dissolving urea in the aqueous suspension; heating the suspension at an elevated temperature to effect hydrolysis of urea into ammonia and carbon dioxide forming a layer of yttrium basic carbonate on the alumina particles; and calcining the basic carbonate-clad particles of alumina at a specified temperature to convert the basic carbonate of yttrium into yttrium oxide.

REFERENCES:
patent: 4851293 (1989-07-01), Egerton et al.
patent: 5320675 (1994-06-01), Dransfiels et al.
patent: 5415775 (1995-05-01), Castillon et al.
patent: 5633084 (1997-05-01), Hiraiwa et al.
J. Daniel et al., Ceramic Transactions, 46, 913-924 (1994).
A. Garg et al., J. Mater. Res., 5(1), 136-142 (1990).

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