Xylomollin derivatives for use as insect feeding deterrents

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Having -c- – wherein x is chalcogen – bonded directly to...

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514460, 514470, A01N 4308, A01N 4316

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active

059656085

ABSTRACT:
Synthetic derivatives or intermediates of xylomollin are identified which can be used as insect feeding deterrents. The identified derivatives or intermediates exhibiting antifeeding activity include glutaraldehyde and carbocyclic or heterocyclic dialdehydes wherein the aldehyde groups are positioned on adjacent carbons of the carbocyclic or heterocyclic rings. The active compounds also include the hemiacetal hemiacetal equivalents, the acetal hemiacetal equivalents and the vinyl ether equivalents of the dialdehydes.

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patent: 5290557 (1994-03-01), Mason et al.
Kubo, I., Miura, I. and Nakanishi, K., The Structure of Xylomollin, a Secoiridoid Hemiacetal Acetal, Journal of the American Chemical Society, Oct. 13, 1976, pp. 6704-6705.
Yuk-Sun Lam, P. and Frazier, J.L., Model Study on the Mode of Action of Muzigadial Antifeedant, Tetrahedron Letters, vol. 28, No. 45, pp. 5477-5480, 1987, Printed in Great Britain.

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