XLi 3 N 2 compounds and their hydrides as hydrogen storage...

Details XLi 3 N 2 compounds and their hydrides as hydrogen storage... XLi 3 N 2 compounds and their hydrides as hydrogen storage...

2006-03-22

2009-11-17

Langel, Wayne (Department: 1793)

Chemistry of inorganic compounds

Rare earth compound

C423S413000

Reexamination Certificate

active

07618607

ABSTRACT:
State-of-the-art electronic structure calculations provide the likelihood of the availability of ScLi3N2, TiLi3N2, VLi3N2, CrLi3N2, MnLi3N2, CoLi3N2, NiLi3N2, CuLi3N2, and ZnLi3N2as compounds for reaction with hydrogen under suitable conditions. Reaction with hydrogen is likely to form stable hydrides of the family ScLi3N2Hn, TiLi3N2Hn, VLi3N2Hn, CrLi3N2Hn, MnLi3N2Hn, FeLi3N2HnCoLi3N2Hn, NiLi3N2Hn, CuLi3N2Hn, and ZnLi3N2Hn, where n is an integer in the range of 1-4. These materials offer utility for hydrogen storage systems.

REFERENCES:
patent: 6946112 (2005-09-01), Chen et al.
Chen et al., “Hydrogen Storage in Metal-N-H Complexes,” 2005, NUS, pp. 1-30.
Rainer Niewa, et al.; Li3[ScN2]; The First Nitridoscandate(III)-Tetrahedral Sc Coordination and Unusual MX2 Framework; Chem. Eur. J. 2003, 4255-4259; 2003 Wiley-VCH Verlag Gmb.
A. Gudat, R. Kniep and A. Rabenau, Li3FeN2, A Ternary Nitride With . . . , Journal of the Less-Common Metals, 161 (1990) 31-36.

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