Wrinkle free-water resistant fabrics and garments

Fabric (woven – knitted – or nonwoven textile or cloth – etc.) – Coated or impregnated woven – knit – or nonwoven fabric which... – Coated or impregnated natural fiber fabric

Reexamination Certificate

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Details

C442S093000, C442S104000, C442S107000, C442S152000, C442S164000, C442S165000, C427S400000, C427S430100, C427S393200, C427S393400, C008S115510, C008S116100, C008S195000

Reexamination Certificate

active

06372674

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to the treatment of textiles, and more particularly to a treatment process and composition which provides a fabric having water repellant, stain resistant, and wrinkle-free properties. Most particularly, the present invention relates to water repellant, stain resistant, and wrinkle-free fabrics which display excellent hand and feel.
2. Description of the Related Art
Various types of processes for the treatment of textiles are well known in the art. U.S. Pat. No. 5,614,591 discloses an example of a durable press process which combines a modified ethylene urea resin, a crosslinking acrylic copolymer, and a catalyst to provide durable press properties to the fabric.
U.S. Pat. No. 5,856,245 discloses an example of a barrier web comprising a fabric that has been treated with a curable shear thinned thixotropic polymer composition, the fabric being substantially impermeable to liquids, permeable to gases and impermeable to all microorganisms.
U.S. Pat. No. 5,869,172 discloses an example of processes for treating a porous substrate which involves controlled placement of modifiers through the manipulation of chemical and physical properties inherent in the modifiers to produce internally coated porous materials. The treatment involves impregnating the porous substrate with a curable thixotopic material and one or more modifying materials to impart desired properties.
U.S. Pat. Nos. 5,874,164 and 5,912,116 provide examples of a barrier web comprising a fabric that has been treated with a curable shear thinned thixotropic polymer composition. The fabric is substantially impermeable to liquids, permeable to gases and impermeable to all microorganisms. The barrier webs are either impermeable to all microorganisms or are impermeable to microorganisms of certain sizes. These patents also disclose fabrics that are capable of selectively binding certain microorganisms, particles or molecules depending upon the binding agents incorporated into the polymer before application to the fabric.
SUMMARY
The present invention is directed to a textile treatment process that imparts water repellant, stain resistant, and wrinkle-free properties as well as aesthetically pleasing hand properties to a fabric made in whole or in part of fibers having a hydroxyl group, such as cellulosic fibers. The present invention is also directed to the resultant fabric of the process.
The fabrics are treated by immersion into an aqueous bath. The fabrics are then preferably dried to their natural regain, and pressed to remove unwanted wrinkles. Thereafter heat is applied to cure the reactants. The bath contains 8-14% of a urea resin, preferably DMDHEU, and 4-10% polytetrafluorethylene, preferably ZONYL® PTFE. A bonding reaction between the urea resin and the hydroxyl group on the fabric is initiated upon immersion of the fabric and strengthened when heat is applied during the drying and curing processes. Preferably the bath contains a buffer to maintain pH in a range of 5-5.5 and a catalyst to speed the reaction.
Objects and advantages of the present invention will become more readily apparent to those skilled in the art upon consideration of the following detailed description which describes a preferred embodiment of the invention.


REFERENCES:
patent: 4562097 (1985-12-01), Walter et al.
patent: 5614591 (1997-03-01), Basinger et al.
patent: 5856245 (1999-01-01), Caldwell et al.
patent: 5869172 (1999-02-01), Caldwell
patent: 5874164 (1999-02-01), Caldwell
patent: 5912116 (1999-06-01), Caldwell
patent: WO99/49124 (1999-09-01), None
patent: WO99/49125 (1999-09-01), None
DuPont, About Dupont Zonyl ©Fluroadditives, pp. 1-3.*
DuPont, Zonyl ©-Flurosurfactant, pp. 1-4.

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