Solid anti-friction devices – materials therefor – lubricant or se – Lubricants or separants for moving solid surfaces and... – Heterocyclic ring compound; a heterocyclic ring is one...
Reexamination Certificate
1998-10-27
2001-07-31
Medley, Margaret (Department: 1714)
Solid anti-friction devices, materials therefor, lubricant or se
Lubricants or separants for moving solid surfaces and...
Heterocyclic ring compound; a heterocyclic ring is one...
C508S462000, C508S517000, C252S067000, C252S068000
Reexamination Certificate
active
06268317
ABSTRACT:
BACKGROUND OF THE INVENTION
The present invention relates to a working fluid comprising a refrigerant and a refrigeration lubricant which is used in a refrigerating cycle equipment of refrigerant compression-type.
In the refrigerating cycle equipments of refrigerant compression-type such as air conditioners, electric refrigerators (freezers), refrigerating or freezing ware houses and refrigerating show cases, hydrocarbons containing a fluorine atom have conventionally been employed as refrigerant.
In particular, hydrocarbons containing a chlorine atom in addition to the fluorine atom have long been employed as the refrigerant having excellent performance such as nonflammability or the like. These chlorofluorocarbons (CFC) and hydrochlorofluorocarbons (HCFC) contain a chlorine atom. It has now been clarified that these refrigerants destruct the ozone layer when they are released to the open air and reached the stratosphere, and the use of them has recently been limited or inhibited globally.
At present, hydrofluorocarbons (HFC) containing no chlorine atom have begun to be employed in stead of these refrigerants. Although the HFC has no potential for destructing the ozone layer, it demonstrates a high green-house effect because its life in the air is long. Thus, the HFC is not necessarily an excellent refrigerant in the viewpoint of preventing the global warming which is a problematic concern in recent years.
In stead of the above-mentioned hydrocarbons containing a halogen atom, hydrocarbons containing no halogen atom, which are inflammable but have an ozone layer depletion potential (ODP) of zero and a very small global warming potential (GWP) as compared to the hydrocarbons containing a halogen atom, are now employed as the refrigerant. The refrigerating cycle equipment employing this refrigerant is practically used as the refrigerator and feasibility of the refrigerant for developing large-size equipment is now under investigation.
With respect to the refrigeration lubricant as a component of the working fluid which is employed together with the refrigerant, mineral oils and alkylbenzene compounds which were conventionally employed as the refrigeration lubricant could not be used with the recent trend for shifting the refrigerant to the ozone layer nondestructive HFC such as R-134a (1,1,1,2-tetrafluoroethane), because they have no compatibility with such refrigerant. In a refrigerating cycle of refrigerant compression-type, a portion of the refrigeration lubricant is discharged from the compressor together with the refrigerant. Therefore, the refrigeration lubricant must not be separated from the refrigerant to stay in the refrigerating cycle (other than the compressor) in order to secure an amount of oil required for lubricating the mechanism of circulating the refrigerant through the refrigerating cycle with a low temperature part and returning the same to the compressor.
For these reasons, it has been believed that the refrigeration lubricant should have compatibility with the refrigerant. In the refrigerating cycle equipment which employs the HFC as the refrigerant, glycol ether oils or polyol ester oils are mainly used as the refrigeration lubricant. In a limited number of equipment, alkylbenzene oils which are incompatible with the HFC refrigerant are used (JP-A-5-157379). In addition, various carbonate oils are proposed as the refrigeration lubricant for the HFC refrigerant (JP-A-3-149295, JP-A-3-247695, and others).
Further, hydrocarbons containing no halogen atom such as ethane, propane, butane, iso-butane and the like are used as the refrigerant. As well as the less polar mineral oils and alkylbenezene oils which have been used with the (hydro) fluorocarbons containing a chlorine atom, the much polar glycol ether oils and polyol ester oils, which have been used with the hydrofluorocarbons containing no chlorine atom, have a high compatibility with the hydrocarbon refrigerant containing no halogen atom. Therefore, it has been believed that there is no problem in selecting the refrigeration lubricant.
In case of employing the above-mentioned refrigeration lubricant, however, its compatibility with the refrigerant is excessive and the amount of the refrigerant to be dissolved in the refrigeration lubricant becomes excessively large. Namely, there is a problem that a refrigerating cycle equipment could not sufficiently demonstrate its performance if a large amount of the refrigerant is charged in the equipment. Further, another problem arises in case wherein the refrigerant leaks from the refrigerating cycle equipment because the hydrocarbons containing no halogen atom such as ethane, propane, butane, iso-butane and the like used as the refrigerant are remarkably inflammable. In other words, it can be presumed that there is a problem in safety because the larger the amount of the refrigerant in the refrigerating cycle equipment is, the larger becomes the amount of leakage in the worst case.
In addition, in a refrigerating cycle equipment employing a HFC refrigerant together with an alkylbenzene oil which has no compatibility with the HFC, the specific gravity of the HFC refrigerant is larger than that of the refrigeration lubricant. Therefore, there is a further problem that an oiling mechanism for a sliding part of a refrigerant compressor, an oil returning mechanism for the refrigeration lubricant component circulating through the refrigerating cycle, or a driving control mechanism becomes complicated.
It is therefore the primary object of the present invention to provide a working fluid which demonstrates preferable performance even with the small amount of the refrigerant containing no halogen atom such as ethane, propane, butane, iso-butane or the like in the refrigerating cycle equipment.
It is another object of the present invention to provide a refrigerating cycle equipment excellent in its safety by the use of the above-mentioned working fluid even in the worst case of refrigerant leakage.
BRIEF SUMMARY OF THE INVENTION
The present invention provides a working fluid for a refrigerating cycle equipment of refrigerant compression-type containing the refrigerant and a refrigeration lubricant for a refrigerator, wherein;
the above-mentioned refrigerant comprises a hydrocarbon having 2 to 4 carbon atoms and no halogen atom, and
the above-mentioned refrigeration lubricant for the refrigerator comprises, as a main component, an ester compound which is incompatible with the above-mentioned refrigerant.
In the above-mentioned ester compound, the number of the carbon atoms constituting ester bond preferably occupies not less than 10 atom % of the whole carbon atoms constituting the above-mentioned ester compound.
Further, it is preferable that the above-mentioned ester compound is a chain (linear) carbonate compound, a cyclic carbonate compound or a cyclic ester compound.
The above-mentioned chain carbonate compound is preferably represented by the formula (1):
wherein R
1
is a methyl group, an ethyl group, an n-propyl group, an iso-propyl group, an n-butyl group, a sec-butyl group or a t-butyl group,
each of R
2
, R
3
and R
4
is independently a hydrocarbon group having 2 to 5 carbon atoms or a hydrocarbon group having 2 to 10 carbon atoms and an ether bond such as alkyloxyalkylene group, poly (oxyalkylene) group and the like, and each of 1, m and n is independently an integer of not less than 0 (wherein, 1, m and n are not 0 at the same time).
It is preferable that said cyclic carbonate compound is represented by the formula (2):
wherein X is a methylene group or an oxygen atom, each of R
5
and R
6
is a hydrogen atom or a methyl group, R
7
does not exist or is —CH
2
O—, —CH
2
O(CH
2
CH
2
O)
p
—(CH
2
CHCH
3
O)
q
, or —CH
2
O{COO—(CH
2
CH
2
O)
p
}
r
—{COO—(CH
2
CHCH
3
O)
q
}
s
— (wherein p and q are not 0 at the same time and each is an integer of 0 to 3 independently, r and s are not 0 at the same time and each is an Integer of 0 to 2 independently), &bgr; is a hydrogen atom or an alcohol residue of hydric value &bgr;, &agr; is an integer of
Kawakami Tetsuji
Nakajima Keizo
Sawai Kiyoshi
Ueno Takayoshi
Akin Gump Strauss Hauer & Feld L.L.P.
Matsushita Electric - Industrial Co., Ltd.
Medley Margaret
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