White organic light-emitting devices using rubrene layer

Details White organic light-emitting devices using rubrene layer White organic light-emitting devices using rubrene layer

2002-07-08

2004-04-13

Kelly, Cynthia H. (Department: 1774)

Stock material or miscellaneous articles

Composite

Of inorganic material

C428S917000, C313S502000, C313S504000, C313S506000, C257S089000

Reexamination Certificate

active

06720092

ABSTRACT:

FIELD OF THE INVENTION
The present invention relates to OLED devices that emit white light.
BACKGROUND OF THE INVENTION
An OLED device includes a substrate, an anode, a hole-transport layer made of an organic compound, an organic luminescent layer with suitable dopants, an organic electron-transport layer, and a cathode. OLED devices are attractive because of their low driving voltage, high luminance, wide-angle viewing and capability for full-color flat emission displays. Tang et al. described this multilayer OLED device in their U.S. Pat. Nos. 4,769,292 and 4,885,211.
Efficient white light producing OLED devices are considered a low cost alternative for several applications such as paper-thin light sources backlights in LCD displays, automotive dome lights, and office lighting. White light producing OLED devices should be bright, efficient, and generally have Commission International d'Eclairage (CIE) chromaticity coordinates of about (0.33, 0.33). In any event, in accordance with this disclosure, white light is that light which is perceived by a user as having a white color.
The following patents and publications disclose the preparation of organic OLED devices capable of emitting white light, comprising a hole-transport layer and an organic luminescent layer, and interposed between a pair of electrodes.
White light producing OLED devices have been reported before by J. Shi (U.S. Pat. No. 5,683,823) wherein, the luminescent layer includes a red and blue light-emitting material uniformly dispersed in a host emitting material. This device has good electroluminescent characteristics, but the concentration of the red and blue dopants are very small, such as 0.12% and 0.25% of the host material. These concentrations are difficult to control during large-scale manufacturing.
Sato et al. in JP 07,142,169 discloses an OLED device, capable of emitting white light, made by sticking a blue light-emitting layer next to the hole- transport layer and followed by a green light-emitting layer having a region containing a red fluorescent layer.
Kido et al. in Science, Vol. 267, p. 1332 (1995) and in APL vol. 64, p. 815 (1994) report a white light producing OLED device. In this device three emitter layers with different carrier transporting properties, each emitting blue, green, or red light, are used to generate white light.
Littman et al. in U.S. Pat. No. 5,405,709 disclose another white emitting device, which is capable of emitting white light in response to hole-electron recombination and comprises a fluorescent in a visible light range from bluish green to red.
Recently, Deshpande et al., in Applied Physics Letters, vol. 75, p. 888 (1999) published white OLED device using red, blue, and green luminescent layers separated by a hole blocking layer.
However, these OLED devices require very small amounts of dopant concentrations, making the process difficult to control for large-scale manufacturing. Also, emission color varies due to small changes in the dopant concentration.
SUMMARY OF THE INVENTION
It is an object of the present invention to produce an effective white light-emitting organic device.
It is another object of this invention to provide an efficient and stable white light producing OLED device with simple structure and which can be reproduced in manufacturing environment.
It has been found quite unexpectedly that white light producing OLED devices with high luminance efficiency and operational stability can be obtained by depositing yellow light-emitting layer adjacent to the blue emission layer.
This object is further achieved by an organic light-emitting diode (OLED) device which produces substantially white light, comprising:
a) a substrate;
b) an anode disposed over the substrate;
c) a hole injecting layer disposed over the anode;
d) a hole-transport layer disposed over the hole injecting layer;
e) a yellow light-emitting layer having rubrene or a derivative thereof greater than 50% by volume of the constituents of such yellow light-emitting layer that emits light in the yellow region of the spectrum and is disposed on the hole-transport layer;
f) a light-emitting layer doped with a blue light-emitting compound, disposed directly on the yellow light-emitting layer;
g) an electron-transport layer disposed over the blue light-emitting layer; and
h) a cathode disposed over the electron-transport layer.
This object is further achieved by an organic light-emitting diode device which produces substantially white light, comprising:
a) a substrate;
b) an anode disposed over the substrate;
c) a hole injecting layer disposed over the anode;
d) a hole-transport layer disposed over the hole injecting layer;
e) a light-emitting layer doped with a blue light-emitting compound, disposed directly on the hole-transport layer;
f) a yellow light-emitting layer having rubrene or a derivative thereof greater than 50% by volume of the constituents of such yellow light-emitting layer that emits light in the yellow region of the spectrum and is disposed on the blue-emitting layer;
g) an electron-transport layer disposed directly over the yellow light-emitting layer; and
h) a cathode disposed over the electron-transport layer.
ADVANTAGES
The following are features and advantages of the present invention:
a simplified OLED device for producing white light by having a yellow light-emitting rubrene layer on the hole-transport layer, or over the electron-transport layer, or over both the hole-transport layer and the electron transport layer; and
an OLED device which is easy to control blue and yellow light-emitting layers.
OLED devices made in accordance with the present invention can be produced with high reproducibility and consistently provide high light efficiency. These devices have high operational stability and also require low drive voltage.


REFERENCES:
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“Red Organic Light-Emitting Diodes Using an Emitting Assist Dopant” by Yuji Hamada et al., Applied Physics Letters, vol. 75, No. 12, Sep. 20, 1999, pp. 1682-1684.
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“White-Light-Emitting Organic Electroluminescent Devices Based on Interlayer Sequential Energy Transfer” by R. S. Deshpande, et al., Applied Physics Letters, vol. 75, No. 7, Aug. 16, 1999, pp. 888-890.
“White Light-Emitting Organic Electroluminescent Devices Using the ploy(N-vinylcarbazole) Emitter Layer Doped with Three Fluorescent Dyes”, by J. Kido et al., Applied Physics Letters, 64 (7), Feb. 14, 1994, pp. 815-817.

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