Wet process of preparing fine particles of ferrite of magnetoplu

Compositions – Magnetic – Iron-oxygen compound containing

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252 626, 252 6262, 252 6263, 252 6264, C04B 3526

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045512604

ABSTRACT:
In preparing fine and plate-shaped particles of a ferrite having the magnetoplumbite structure by hydrothermal treatment of a powder of .gamma.-Fe.sub.2 O.sub.3 or (FeO).sub.x.Fe.sub.2 O.sub.3, where O<x.ltoreq.1, and a compound of Ba, Sr or Pb in an aqueous alkali solution, Sn.sup.4+, or Sn.sup.4+ and M.sup.2+ such as Fe.sup.2+, Cu.sup.2+ or Zn.sup.2+, are introduced into the reaction system of the hydrothermal treatment such that Fe.sup.3+ in the obtained ferrite are partly substituted by Sn.sup.4+ or M.sup.2+ -Sn.sup.4'. The substitution has the effect of lowering the coercive force of the ferrite powder to a level suitable for use in magnetic recording media of the perpendicularly magnetizing recording type. By using an iron oxide powder having a mean particle size not larger than 500 .ANG. with addition of a surface-active agent, the particle size of the ferrite powder can be reduced to about 0.2 .mu.m.

REFERENCES:
patent: 4341648 (1982-07-01), Kubo et al.
patent: 4407721 (1983-10-01), Koike et al.
"Structural and Magnetic Studies of Hydrothermally Synthesized New Ferrites", Research Bulletin of Nagaoka Institute of Science and Technology, No. 4 (1982).

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