Wet oxidation process for ACN waste streams

Liquid purification or separation – Processes – Chemical treatment

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Details

210904, 210908, C02F 172, C02F 174

Patent

active

051924536

ABSTRACT:
A process is disclosed which limits the corrosion of the materials of construction of a wet oxidation system treating wastewaters. The process is particularly useful in the wet oxidation treatment of ammonium sulfate containing wastes such as acrylonitrile wastewaters. The wastewater is mixed with an oxygen containing gas such that a substantial residual oxygen gas concentration is maintained from before the stream-gas mixture is heated for wet oxidation until after the oxidized stream-gas mixture is cooled and separated. Preferably, in the treatment of acrylonitrile waste water the shutdown procedure comprises cooling said waste stream by introducing an aqueous liquid substantially free of organic impurities and containing a basic material.

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S. L. Lade et al., "Sustainable Development At Work: Operating Experience with the Zimpro Wet Oxidation Plant", Oct. 1991.
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The Reactor Magazine, "Industrial Waste Water Treatment, Helping Steel Kick the Coke Oven Gas Habit", No. 41, Feb. 1979.
"Reactor/Wastewater Treatment News From Zimpro/Passavant Inc."; No. 68, Jun. 1990.
"Lo Prox (Low Pressure Wet Oxidation for Waste Water Pretreatment)", Bertrams.

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