Metal treatment – Stock – Aluminum base
Reexamination Certificate
2000-10-18
2003-03-11
Wyszomierski, George (Department: 1742)
Metal treatment
Stock
Aluminum base
C420S532000, C420S533000, C420S541000, C420S542000, C420S543000, C148S440000
Reexamination Certificate
active
06531004
ABSTRACT:
The invention relates to a weldable, corrosion-resistant, high-magnesium-content aluminum-magnesium alloy, which contains a ternary aluminum-scandium-zirconium phase as the essential component. Such an alloy is known from U.S. Pat. No. 5,624,632, for example, and is of interest above all for applications in aeronautics due to its low density, high strength and corrosion resistance. Adding rare earth or rare earth-like elements generates dispersoids in the aluminum-magnesium alloy, which produce a higher strength and corrosion resistance according to the above US patent. The above US patent makes no statement as to the weldability of such an alloy.
The object of this invention is to provide a weldable, corrosion-resistant, high-magnesium-content aluminum-magnesium alloy, which is at least as good as the known alloy in terms of strength and corrosion behavior, and exhibits a high recrystalization threshold to go along with a good weldability. This object is achieved by an aluminum-magnesium alloy according to claim
1
.
In comparison to the known alloy, this new alloy exhibits above all a distinctly lower manganese content, wherein an improved corrosion resistance was surprisingly found, primarily in the sensitized state of the parts made out of this alloy, e.g., when cold-formed parts are subjected to an elevated temperature over a prolonged period. It is assumed that these positive properties are determined primarily by the ratio of manganese to scandium. An improved corrosion resistance is observed at a ratio of Mn to Sc<2. Along with acting as a grain growth inhibitor, the titanium content not present in the known alloy helps to increase strength, since titanium can replace the zirconium in the ternary Al—Sc—Zr phase, wherein the solubility of titanium is lower than that of zirconium however.
The addition of Cu and/or Zn increases the strength, which can be traced back to the known high strength of the Al—Cu or Al—Zn phase. The respective upper concentration limits are selected to prevent the Cu from diminishing the weldability, and the Zn from diminishing the corrosion resistance.
A particularly strong and corrosion-resistant alloy contains at least 0.15% w/w scandium. A component from the lanthanide series is preferably added in amounts ranging from 0.05 and 0.35% w/w, wherein this range relates to the total mixture when using a lanthanide mixture. The alloy tolerates silicon contamination of up to 0.1% w/w; primarily the dynamic properties deteriorate above this level.
REFERENCES:
patent: 4645543 (1987-02-01), Watanabe et al.
patent: 5620652 (1997-04-01), Tack et al.
patent: 5624632 (1997-04-01), Baumann et al.
patent: 63179040 (1988-07-01), None
Database WPI Section Ch, Week 7710 Derwent Publications Ltd., XP-002127941, p. 23, AN 1977-17364Y & JP52011143 A (Nippon Light Metal Res Lab).
Database WPI Section Ch, Week 9808 Derwent Publications Ltd. XP002127942 & RU 2081934 c (Light Alloys Inst Stock Co).
Cherkasov V.V., et al. “Special Fearutes of the Structure Formation and Properties . . . ”Metal Science and Heat Treatment.
Patent Abstracts of Japan of 63248593 of Octover 14, 1998.
Patent Abstracts of Japan of JP 63-179040 Dated: Jul. 23, 1988.
Brockhaus der Naturwissenschaften und der Technik, p. 161 (1965) F.A. Brockhaus Wiesbaden.
Gschneidner, Jr., K.A. “A critical Review of the Alloy Systems of the Rare Earth, Scandium and Yttrium Metals,” in Rare Earth Alloys (1961) pp XI & 12.
Filatov Yuri
Lenczowski Blanka
Rauh Rainer
Yelagin Viktor
Zakharov Valeri
Combs Morillo Janelle
EADS Deutschland GmbH
Ladas & Parry
Wyszomierski George
LandOfFree
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