Compositions: coating or plastic – Coating or plastic compositions – Marking
Reexamination Certificate
2002-12-19
2004-03-23
Bell, Mark L. (Department: 1755)
Compositions: coating or plastic
Coating or plastic compositions
Marking
C106S031730, C106S031750, C106S031860
Reexamination Certificate
active
06709503
ABSTRACT:
FIELD OF THE INVENTION
The invention relates to water based ink compositions for use in heat set/offset lithographic printing processes.
BACKGROUND OF THE INVENTION
The heat set printing process was first introduced in the 1950's and is now well established in the printing industry for the production of magazines, catalogues and brochures. The process yields high gloss, high quality prints and involves oven drying of the printed product.
In high speed web-offset printing presses, ink is applied to both surfaces of the web substrate simultaneously. To dry the ink before the substrate contacts a solid surface, the printed or coated web is passed through a float or floater type oven under tension and floated between cushions of hot air. Upon leaving the oven, the web must be cooled before further processing, such as sheeting, folding, or rewinding. Thus, the web is passed over one or more chill drums or rolls, i.e., internally cooled drums which reduce the web temperature from about 93° C. to about 32° C. Thus, heat set inks must fulfill exacting criteria to meet the high speed of press runs, the oven drying and required subsequent chilling and still meet the print quality standards. Further discussion of heat set inks and the heat set printing process can be found at
The Printing Ink Manual,
edited by R. H. Leach and R. J. Pierce, paces 571-576, 5th edition, (Blueprint, 1993).
Generally, lithographic heat-set/offset printing inks predominantly contain petroleum distillates. The fountain solutions typically contain a desensitizer, salts, and glycols. The use of water based inks allows the printer to avoid many of these volatile organic components (“VOCs”) and their byproducts but requires additional equipment such as a humidity control chamber.
The offset lithographic printing process has always presented a unique challenge to ink formulators since the process utilizes a plan ographic printing plate, i.e. the image and non-image areas are in the same plane on the image carrier, and two fluids are concurrently utilized as discussed above. Water based inks have been developed, but remain slow drying and high in tack.
U.S. Pat. No. 5,725,646, which is incorporated herein by reference, describes a way of stabilizing a water based offset ink composition without drying up on a conventional multiple roller ink train using use a re-wetting agent, namely hydroxyethylethylene urea (“HEEU”). Since this re-wetting agent does not dry, it remains in the final film making it susceptible to poor water resistance. High levels of VOCs emanating from the oil-based ink and the aqueous fountain solution were reduced as was the difficulty in controlling the ink/water balance, while preserving the principal advantage of the conventional lithographic printing process, i.e. high surface energy differential between the image and non-image areas of the printing plate. However, the use of conventional re-wetting agents, such as glycols and glycol ethers not only imparts poor water resistance to the final film, but also increases the tack of the formulations, thereby limiting its use on high speed presses.
U.S. Pat. No. 6,444,021, which is incorporated by reference, describes a newspaper ink composition containing a humectant and a modified soybean oil based resin so as to eliminate the need for the humidity control (chamber) associated with water based inks while allowing the use of existing, multiple roller press set-ups. Drying problems remained however as the humectant takes longer to dry once the ink has printed on coated papers.
U.S. Pat. No. 6,444,022 B1 which is incorporated by reference, describes a modified linseed oil reacted with polyglycols. In this manner, the benefits of including HEEU in the composition could be obtained without sacrificing risking water washability. However, dry times remain higher than required for heatset/offset printing.
Thus, there exists a need for a heatset/offset printing ink which can be printed at high speed and dry quicker than the prior art referenced above while still maintaining low tack for ink transfer and water resistance after printing.
SUMMARY OF THE INVENTION
It is an object of the present invention to describe heat set ink compositions which preserve the advantages of current water based ink systems containing HEEU, such as elimination of VOCs in the pressroom, while also eliminating the need for a humidity chamber in a manner which does not rely upon modified soybean oil based resin. It is an additional object of this invention to allow the continued use of existing conventional multiple roller printing systems.
A water based heat set offset lithographic ink composition according to the present invention comprises: (a) water; (b) fumarated rosin resins; (c) a modified linseed oil; (d) hydroxyethylethylene urea; (e) a dibutylated benzoguanamine; (f) p-toluene sulfonic acid (PTSA); and (g) pigment. The present invention is also directed to a waterbased heatset offset lithographic ink composition comprising: (a) water; (b) polyamide resins; (c) hydroxyethylethylene urea; (d) a modified linseed oil; (e) a dibutylated benzoguanamine; and (f) pigment.
DETAILED DESCRIPTION OF THE INVENTION
It has been found that the use of hydroxyethylethylene urea in conjunction with benzoguanamine resin or with certain polyamide resins allows the formulation of a water based heatset lithographic ink which can be used in existing conventional multiple roller systems without the aid of a humidity chamber. Once printed, the ink has excellent rub and water resistance.
Water
The water based printing inks of the present invention contain water to act as a rheology and/or a surface energy modifier of the ink composition and to enhance the water washability of the ink. The water may be an added component or be contributed by one of the other components of the composition such as residual water from a pigment flush or press cake.
Resins for Pigment Bonding
The fumarated rosin resin in the present invention is a binder bonded to a pigment. Suggested binders to which the selected pigment may be bonded include, but are not limited to, water-soluble polyamide resins, rosin resins, rosin salts, tall oil resins, methacrylic resins, styrene-acrylic resins, polystyrenesulfonic acid and its salts, and acrylic or vinyl emulsion polymers prepared from monomers selected from the group consisting of acrylic acid esters, methacrylic acid esters, acrylic acid esters of polyhydric alcohols, methyl methacrylate, styrene, vinyl styrene, and vinyl acetate, and mixtures thereof. Particularly preferred binders are polyamide resins specially developed for use in graphic arts compositions, such as those resins sold under the trademark GAX™ such as GAX™ 12-513, available from FitzChem Corporation, Elmhurst, Ill., U.S.A., and fumarated rosin resins, available from Akzo Nobel Chemicals, Inc., Chicago, Ill.
Rewetting Agent
The composition of the present invention includes hydroxyethyl ethylene urea as a rewetting agent. The hydroxyethylethylene urea (HEEU) improves flow and increases open time on the rollers. While not wishing to be bound by theory, it is believed that the HEEU rewetting agent serves as a plasticizer by providing surface continuity to the dry film on the substrate.
Modified Linseed Oil
The invention includes a modified linseed oil to address problems otherwise associated with the inclusion of HEEU such as poor water resistance. The modified linseed oil also helps to reduce the ink's tack. The modified linseed oil according to the present invention comprises the reaction product of polyglycol and linseed oil.
The modified linseed oil according to the present invention may also include lithium ricinoleate, phthalic anhydride and triphenyl phosphate. Preferred modified linseed oils include DV 1469, manufactured by Reichold Inc., Durham, N.C.
Dibutylated Benzoguanamine
The composition of the invention includes dibutylated benzoguanamine. The dibutylated benzoguanamine of the invention crosslinks with HEEU. The dibutylated benzoguanamine. The presence of water prevents this crosslinking
Babij Hugo
Krishnan Ramasamy
Yamat Marilyn
Bell Mark L.
Faison Veronica F.
Persley Sidney
Sun Chemical Corporation
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