Water-soluble or water-dispersible acrylic dispersants...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S220000, C526S320000, C526S329500, C526S329600, C526S333000, C526S307500, C526S317100, C526S318000, C524S005000, C524S558000, C524S556000, C524S560000

Reexamination Certificate

active

07619045

ABSTRACT:
The present invention relates to a process for the preparation in aqueous solution of water-soluble acrylic polymers or for the preparation in aqueous dispersion of water-dispersible acrylic co-polymers, polymerised from, the total being 100 mol %:a) 5 to 70 mol % of one or more monomer(s) (A) which are (alkoxy)polyalkylene glycol (meth)acrylates and/or ((alkoxy)polyalkylene glycol)(meth)acrylamides;b) 5 to 95 mol % of one or more unsaturated carboxylic monomer(s) (B); andc) 0 to 85 mol % of one or more hydrophobic monomer(s) (C) which are water insoluble, in the absence of a chain-transfer agent, and in the presence of a sufficient amount of a water-soluble alkoxyamine, until a conversion of at least 90% by weight of the monomers (A), (B) and (C) is obtained. The polymer has a polydispersity indexMw/Mnadvantageously <2 and anMnof between 10 000 g/mol and 50 000 g/mol. Alternately, only some of the monomer (>50%) is converted by the alkoxyamine and the polymerization is completed by a conventional radical initiator. The polymer obtained has a polydispersity indexMw/Mn<6, advantageously <5, preferably <4, and anMwof between 10 000 g/mol and 500 000 g/mol and advantageously between 30 000 and 150 000 g/mol.

REFERENCES:
patent: 4581429 (1986-04-01), Solomon et al.
patent: 6376581 (2002-04-01), Tanaka et al.
patent: 6548589 (2003-04-01), Widmer et al.
patent: 6673885 (2004-01-01), Shibata et al.
patent: 7288585 (2007-10-01), Moad et al.
patent: 2006/0142511 (2006-06-01), Couturier et al.
patent: WO 98/07758 (1998-02-01), None
http://www.galleries.com/minerals/sulfates/ gypsum/gypsum.htm.
http://www.ingentaconnect.com/content/k1u/glac/2003/00000060/F0020011/00487272.

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