Water-soluble macromonomers containing terminal unsaturation...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Compositions to be polymerized by wave energy wherein said...

Reexamination Certificate

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C522S089000, C522S188000

Reexamination Certificate

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07875659

ABSTRACT:
This invention provides a water-soluble macromonomer having terminal unsaturation obtained by polymerization of monomers in the presence of inclusion complex of chain transfer agent in aqueous system. Hydrophobic chain transfer agent AMSD forms an inclusion complex with methylated cyclodextrin. The complexation enhances its solubility in water and enables the polymerization of water-soluble monomers in aqueous medium. After polymerization cyclodextrin is removed and the macromer with terminal unsaturation obtained can be used further for copolymerization with any vinyl monomer.

REFERENCES:
patent: 4000220 (1976-12-01), Shoji et al.
patent: 4001349 (1977-01-01), Severini et al.
patent: 4170582 (1979-10-01), Mori et al.
patent: 4427826 (1984-01-01), Echte et al.
patent: 4547327 (1985-10-01), Bruins et al.
patent: 4680352 (1987-07-01), Janowicz et al.
patent: 4694054 (1987-09-01), Janowicz
patent: 4808656 (1989-02-01), Kania et al.
patent: 5264530 (1993-11-01), Darmon et al.
patent: 6100350 (2000-08-01), Wilczek et al.
patent: 6872789 (2005-03-01), Brinkhuis et al.
patent: 6884562 (2005-04-01), Schadt et al.
patent: 7022762 (2006-04-01), Van Aert et al.
patent: 2002/0072580 (2002-06-01), Aert et al.
patent: 02/094887 (2002-11-01), None
patent: 03/076922 (2003-09-01), None
Jeromin, J., et al. “Cyclodextrins in Polymer Synthesis: Free Radical Polymerization of a N-Metharcryloyl-11-aminoundecanoic Acid/β-Cyclodextrin Pseudorotaxane in an Aqueous Medium.”Macromolecules(1999) vol. 32, pp. 5236-5239.
Lau, Willie “Emulsion Polymerization of Hydrophobic Monomer.”Macromol. Symp. (2002) vol. 182, pp. 283-289.
Leyer, R. J., et al. “Emulsion polymerization of hydrophobic monomers like stearyl acrylate with cyclodextrin as a phase transfer agent.”Macromol. Chem. Phys. (2000) vol. 201, pp. 1235-1243.
Meijs, G .F., et al. “Preparation of Controlled Molecular Weight, Olefin-Terminated Polymers by Free Radical Methods. Chain Transfer Using Allylic Sulfides.”Macromolecules(1988) vol. 21, pp. 3122-3124.
Kapse, G.W., et al. “Studies on mould resistant emulsion paints.”Paint India(1983) vol. 33, pp. 5-7.
Watanabe, Y., et al. “Addition-Fragmentation Chain Transfer in Free Radical Styrene Polymerization in the Presence of 2,4-Diphenyl-4-methyl-1-pentene.”Chemistry Letters(1993) pp. 1089-1092.
Spychaj, T. “Low Molecular Weight Polymers of Acrylic Acid and Copolymers with Styrene.”Progress in Organic Coatings(1989) vol. 17, pp. 71-88.
Sato, E., et al. “Macromonomer Synthesis Using Oligomers of ω-Unsaturated Methacrylate as Addition-Fragmentation Chain Transfer Agents: Increased Efficiency by Manipulation of Steric Hindrance.”Macromolecules(2004) vol. 37, pp. 2363-2370.
Storsberg, J., et al. “Cyclodextrins in Polymer Synthesis: Supramolecular Cyclodextrin Complexes of Pyrrole and 3,4-Ethylenedioxythiophene and Their Oxidative Polymeriaation.”Advanced Materials(1999) vol. 12, 3 pages.
Ohnaga, T., et al. “Synthesis of poly(vinyl acetate) macromonomers and preparation of poly(vinyl acetate) grafted copolymers and poly (vinyl alcohol) grafted copolymers.”Polymer(1996) 37 (16) 3729 , 7 pages.
Meijs, G. F.,et al. “Use of Substituted Allylic Sulfides to Prepare End-Functional Polymers of Controlled Molecular Weight by Free-Radical Polymerization.”Macromolecules(1991) vol. 24, pp. 3689-3695.
Meijs, G. F., et al. “The use of activated benzyl vinyl ethers to control molecular weight in free radical polymerizations.”Makromol. Chem. (1990) vol. 191, pp. 1545-1553.
Baussard, J., et al. “New chain transfer agents for reversible addition-fragmentation chain transfer (RAFT) polymerisation in aqueous solution.”Polymer(2004) 45, pp. 3615-3626.
Fischer, J.P., et al. “Kinetik der radikalischen Copolymerisation α-substituierter Styrole mit Styrol.”Die Makromolekulare Chemie(1972) 155, pp. 239-257.
Glockner, P., et al. “Cyclodextrins in polymer chemistry: Influence of methylatedβ-cyclodextrin as host on the free radical coploymerization reactivity ratios of isobornyl acrylate and butyl acrylate as guest monomers in aqueous medium.”Macromol. Rapid Commun. (1999) 20, pp. 602-605.
Glockner, P., et al. “Cyclodextrins in polymer synthesis: Free radical polymerization of methylated β-cyclodextrin complexes of methyl methacrylate and styrene, controlled by dodecanethiol as the chain-transfer agent in aqueous medium.”Macromol. Chem. Phys. (2000) 201, pp. 2455-2457.
Glockner, P., et al. “Cyclodextrins in Polymer Synthesis: Free-Radical Polymerization of Methylated β-Cyclodextrin Complexes of Methyl Methacrylate and Styrene Controlled by N-acetyl-L-cysteine . . . in Aqueous Medium.”Macromolecules(2000) 33, pp. 4288-4290.
Jeromin, J., et al. “Cyclodextrins in polymer synthesis: free radical polymerisation of cyclodextrin complexes of cyclohexyl and phenyl methacrylate in aqueous medium.”Macromol. Rapid Commun. (1998) 19, pp. 377-379.
Jeromin, J., et al. “Cyclodextrins in polymer synthesis: Free radical polymerization of cyclodextrin complexes with N-methacryloyl-11-aminoundecanoic acid or N-methacryloyl-1-aminononane as guest monomers.”Macromol. Chem. Phys. (1998) 199, pp. 2641-2645.

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