Water insoluble mono azo and disazo dyes containing cinnamonitri

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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106288Q, 106308Q, 260152, 260155, 260164, 260165, 260163, 260186, 260191, 260193, 260196, 260205, 260206, 260207, 2602071, 2602075, 260208, 260465E, 260465G, 260465K, C09B 2908, C09B 2936, C09B 2938, C09B 3312

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040101517

ABSTRACT:
Dyestuffs of the general formula: ##STR1## IN WHICH THE RADICAL --CH=--CN is fixed in the 4- or 5-position, X represents a hydrogen or chlorine atom, the benzene nucleus A is unsubstituted or substituted by at least one chlorine atom or alkyl, alkoxy or acylamino group, m is the number 0 or 1, and B represents the residue of a coupling compound containing no sulphonic or carboxylic acid group.
The dyestuffs in which m represents zero may be prepared by diazotizing a base of the formula: ##STR2## and coupling the diazo derivative with a coupling compound BH wherein X and B have the same significance as set out above.
The dyestuffs in which m is equal to 1 may be prepared by coupling the diazo derivative of a base of the formula: ##STR3## with an amine of the formula: ##STR4## diazotizing the amino-monoazo dyestuff thus obtained and coupling with a coupling compound BH wherein ##STR5## have the same significance as set out above. The dyestuffs may be used for the coloration of synthetic fibres.
3-amino-cinnamonitrile or 3-amino-4-chloro-cinnamonitrile or 4-amino-3-chloro-cinnamonitrile. These may be prepared by Meerwein's reaction between acrylonitrile and a diazonium chloride of m- or p-nitraniline, dehydrohalogenation by means of an alkali and then reduction of the nitro group.

REFERENCES:
patent: 3578654 (1971-05-01), Feure

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