Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1974-04-08
1977-03-01
Higel, Floyd D.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
106288Q, 106308Q, 260152, 260155, 260164, 260165, 260163, 260186, 260191, 260193, 260196, 260205, 260206, 260207, 2602071, 2602075, 260208, 260465E, 260465G, 260465K, C09B 2908, C09B 2936, C09B 2938, C09B 3312
Patent
active
040101517
ABSTRACT:
Dyestuffs of the general formula: ##STR1## IN WHICH THE RADICAL --CH=--CN is fixed in the 4- or 5-position, X represents a hydrogen or chlorine atom, the benzene nucleus A is unsubstituted or substituted by at least one chlorine atom or alkyl, alkoxy or acylamino group, m is the number 0 or 1, and B represents the residue of a coupling compound containing no sulphonic or carboxylic acid group.
The dyestuffs in which m represents zero may be prepared by diazotizing a base of the formula: ##STR2## and coupling the diazo derivative with a coupling compound BH wherein X and B have the same significance as set out above.
The dyestuffs in which m is equal to 1 may be prepared by coupling the diazo derivative of a base of the formula: ##STR3## with an amine of the formula: ##STR4## diazotizing the amino-monoazo dyestuff thus obtained and coupling with a coupling compound BH wherein ##STR5## have the same significance as set out above. The dyestuffs may be used for the coloration of synthetic fibres.
3-amino-cinnamonitrile or 3-amino-4-chloro-cinnamonitrile or 4-amino-3-chloro-cinnamonitrile. These may be prepared by Meerwein's reaction between acrylonitrile and a diazonium chloride of m- or p-nitraniline, dehydrohalogenation by means of an alkali and then reduction of the nitro group.
REFERENCES:
patent: 3578654 (1971-05-01), Feure
Brouard Claude Marie Henri Emile
Leroy Jean Marie Louis
Stiot Jean-Pierre Henry
Higel Floyd D.
Produits Chimiques Ugine Kuhlmann
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