Water gas shift reaction employing intercalated metal carbonyl c

Details Water gas shift reaction employing intercalated metal carbonyl c Water gas shift reaction employing intercalated metal carbonyl c

1981-11-25

1983-11-15

Mars, Howard T.

Compositions

Gaseous compositions

Carbon-oxide and hydrogen containing

C01B 316

Patent

active

044154739

ABSTRACT:
Transition metal carbonyl clusters intercalated with lamellar material such as graphite or smectites are prepared by reacting an intercalate of a transition metal halide with carbon monoxide at elevated temperature and at ambient to superatmospheric pressure. The intercalated complexes are useful in the catalysis of a variety of organic reactions including the water gas shift reaction, hydrogenation, hydroformylation, methanation, and so forth.

REFERENCES:
patent: 3539298 (1970-11-01), Fenton
patent: 3847963 (1974-11-01), Lalancette
patent: 4223001 (1980-09-01), Novotny et al.
patent: 4226845 (1980-10-01), Laine
Canadian Patent Record II 318433, Dec. 29, 1931.
Pettit et al, Inorganic Compounds with Unusual Properties II, 1979 pp. 121-130 (Advances in Chemistry Series 173).
Laine et al, J.A.C.S., 99, pp. 252-253 1977.

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