Water-dilutable, crosslinkable binder resin

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525285, 525298, 525303, 5253273, 5253305, 106 1413, 10628725, C09D13102, C09D13700, C08F21802, C08F22204

Patent

active

051771527

ABSTRACT:
The present invention pertains to a crosslinkable binder resin comprising an acrylate copolymer backbone having as pendant groups water soluble half esters of dicarboxylic acid and crosslinkable olefinic groups which contain an activated ethylenic unsaturation, such as (meth)acryloyl groups. The (meth)acryloyl groups can be crosslinked by polyfunctional crosslinking agents such as amino or blocked amino crosslinkers. The water-soluble half esters preferably are formed by the reaction of pendant hydroxy groups with unsaturated cyclic anhydrides (the unsaturation providing an additional crosslinking site). The (meth)acryloyl groups preferably are formed by the reaction of pendant epoxy groups with (meth)acrylic acid or derivatives thereof.

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Jerry March, Advanced Organic Chemistry, Reactions, Mechanisms, and Structure, Third Ed., 1985, pp. 664-713.

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