Water-compatible solvents for film-forming resins and resin solu

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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106311, 260 296H, 260 296E, 260 296ME, 260 314R, 260 318G, C09D 340, C09D 348, B01F 100

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040050513

ABSTRACT:
The dimethyl ethers of succinic, glutaric and adipic acids show a great increase in their water miscibility when they are mixed with either 6-hydroxycaproic acid methyl ester, one or more of the glycol ethers, diglycol ethers and glycol ether acetates, or both 6-hydroxycaproic acid methyl ester and one or more of the glycol ethers, diglycol ethers and glycol ether acetates. These dimethyl esters are, accordingly, substituents for the glycol ether derivatives in water-miscible solvents for film-forming resins. They may provide up to 80% by weight of the non-water components of the solvent. They may be produced at the same time as the methyl ester of 6-hydroxycaproic acid in a single esterification step by esterifying a fraction of acids derived from the waste salt solutions of cyclohexanone manufacture, as described in a related application, Ser. No. 372,021, now U.S. Pat. No. 3,859,335.

REFERENCES:
patent: 3106486 (1963-10-01), Harren et al.
patent: 3150110 (1964-10-01), Becker et al.
patent: 3223083 (1965-12-01), Cobey
patent: 3312652 (1967-04-01), Coney et al.
patent: 3723379 (1973-03-01), Althouse et al.
patent: 3746725 (1973-07-01), Eilers et al.
"Encyclopedia of Polymer Science and Technology" John Wiley and Sons, Inc. (1969) vol. 10, p. 247.

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