Wastewater treatment

Liquid purification or separation – Processes – Making an insoluble substance or accreting suspended...

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55 53, 55 70, 210718, 210724, 210726, 210903, 210906, 210915, 423321R, C02F 120, C02F 152

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046576800

ABSTRACT:
A method is provided for the treatment of wastewater of pH ranging from about 1.5 to 3 containing at least about 100 ppm phosphorus as phosphate ions, at least about 50 ppm fluorine as fluoride ions and ammonia in excess of about 15 ppm NH.sub.3 (N)--T, the method comprising removing the phosphate and fluoride ions from the wastewater in a two-stage precipitation step; the first stage precipitation being conducted at a pH ranging from about 3.5 to 6.5 using an alkaline material selected from the group consisting of limestone (CaCO.sub.3) and lime [CaO or Ca(OH).sub.2 ] sufficient to form a precipitate which is removed to provide a filtrate of the wastewater which is treated in a second stage precipitation at a pH of at least about 10.5 using lime as the alkaline material sufficient to form a precipitate which is removed to provide substantially a clear effluent containing ammonia. The method also includes, if necessary, treating the ammonia-containing effluent with an alkaline material selected from the group consisting of lime and caustic sufficient to raise the pH to provide a free ammonia equivalence (FAE) of at least about 12.4; the free ammonia equivalence being determined as follows:

REFERENCES:
patent: 3551332 (1970-12-01), Baumann
patent: 3725265 (1973-04-01), Legal
patent: 4045341 (1977-08-01), Tsuruta et al.
patent: 4093544 (1978-06-01), Ross
patent: 4306978 (1981-12-01), Wurtz
patent: 4320012 (1982-03-01), Palm et al.
Mooney et al., "Removal of F & P from H.sub.2 PO.sub.4 Wastes with 2-Stage Lime Treatment," Ind. Wastes Conf., Purdue University, 1978, pp. 286-295.
Culp et al., Handbook of Advanced Wastewater Treatment, 2nd Edition, Von Nonstrand Reinhold Company, pp. 298-316.
Williams, Waste Production & Disposal in Mining, Milling & Metallurgical Industries, Miller Freeman Publications, 1975.
Process Design Manual for Nitrogen Control, U.S. EPA, Oct. 1975.

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