Cleaning compositions for solid surfaces – auxiliary compositions – Cleaning compositions or processes of preparing – For cleaning a specific substrate or removing a specific...
Reexamination Certificate
2002-06-13
2004-06-08
Hardee, John R. (Department: 1751)
Cleaning compositions for solid surfaces, auxiliary compositions
Cleaning compositions or processes of preparing
For cleaning a specific substrate or removing a specific...
C510S446000, C510S507000, C510S515000
Reexamination Certificate
active
06746995
ABSTRACT:
FIELD OF THE INVENTION
This invention relates to wash cycle unit dose laundry compositions for softening or conditioning fabrics. More particularly, this invention relates to unit dose fabric softening compositions which are compacted granular compositions suitable for use in the wash cycle of an automatic washing machine.
BACKGROUND OF THE INVENTION
Detergent compositions manufactured in the form of compacted detergent powder are known in the art. U.S. Pat. No. 5,225,100, for example, describes a tablet of compacted powder comprising an anionic detergent compound, which will adequately disperse in the wash water.
U.S. Pat. Nos. 6,258,767; 6,294,516 and 6,291,421 assigned to Colgate-Palmolive Company describe unit dose granular and encapsulated liquid fabric softening compositions suitable for use as an additive to the wash cycle of a washing machine, or during hand washing of laundry.
Another possible option for providing a unit dose softener apart from the wash cycle is to introduce the softening ingredients directly into the rinse cycle. But, for this type of product to be effective several practical requirements must be met. To begin with, the size and shape of the unit dose container must be readily compatible with the geometry of a wide variety of rinse cycle dispensers designed for home washing machines in order to insure its easy introduction into the dispenser. Moreover, in common with the general use of rinse cycle softeners, it is necessary to clean the rinse dispenser on a regular basis to avoid residue from accumulating within the dispenser or even, at times, prevent bacterial growth from occurring.
Still further, a unit dose composition for the rinse cycle must be formulated to readily dispense its contents upon contact with water in a period of time corresponding to the residence time of the unit dose in the dispenser, namely, the period of time during which water enters and flows through the rinse cycle dispenser. The aforementioned practical requirements have to date not been successfully met with any commercially available product and hence there remains a need in the art for a unit dose softener capable of activation in the rinse cycle.
Laundry detergent compositions which further include a fabric softener to provide softening or conditioning of fabrics in the wash cycle of the laundering operation are well-known in the art and described in the patent literature. See, for example, U.S. Pat. No. 4,605,506 to Wixon; U.S. Pat. No. 4,818,421 to Boris et al. and U.S. Pat. No. 4,569,773 to Ramachandran et al., all assigned to Colgate-Palmolive Co., and U.S. Pat. No. 4,851,138 assigned to Akzo. U.S. Pat. No. 5,972,870 to Anderson describes a multi-layered laundry tablet for washing which may include a detergent in the outer layer and a fabric softener, or water softener or fragrance in the inner layer. But, these type of multi-benefit products suffer from a common drawback, namely, there is an inherent compromise which the user necessarily makes between the cleaning and softening benefits provided by such products as compared to using a separate detergent composition solely for cleaning in the wash cycle and a separate softening composition solely for softening in the rinse cycle. In essence, the user of such detergent softener compositions does not have the ability to independently adjust the amount of detergent and softener added to the wash cycle of a machine in response to the cleaning and softening requirements of the particular wash load.
Some attempts have been made in the art to develop wash cycle active fabric softeners, typically in powder form. But, these type products are characterized by the same inconvenience inherent with the use of powered detergents, namely, problems of handling, caking in the container or wash cycle dispenser, and the need for a dosing device to deliver the desired amount of active softener material to the wash water. It has now been found that softening of laundry can be effected in the wash cycle with a flexibility which is independent of the detergent dosage, and with great convenience by the consumer by the use of a compacted granular unit dose wash cycle softener which avoids the common problems associated with the pouring and handling of granular or liquid detergent compositions, and which provides enhanced dispersibility of the compacted granular composition in the wash water.
SUMMARY OF THE INVENTION
There is provided herein a unit dose wash cycle fabric softening composition for softening or conditioning fabrics which is readily dispersible during hand wash or in the wash cycle of an automatic washing machine, said unit dose comprising a compacted granular fabric softener composition comprising a softening clay component in an amount sufficient to form a unit dose capable of providing effective softening or conditioning of fabrics in the wash cycle of said washing machine, and wherein said compacted fabric softener composition is formed from granules of softener, which granules are formed from a powder of said clay component wherein the amount of moisture in said clay component is from about 3% to about 10%, by weight, and wherein the total amount of moisture in the compacted fabric softener composition is from about 3% to about 25% by weight.
The moisture levels of the clay component and compacted softener composition as described herein are determined by measuring the weight loss after heating the particular material at 105° C. for 4 hours in a closed oven.
In a preferred embodiment the unit dose fabric softening composition is characterized by being in the form of a tablet and having no discrete outer layer surrounding the fabric softener comprised of an alkaline material such that the pH of the wash water is increased upon dissolution of said outer layer in said wash water.
The term “granular” as used herein in describing the fabric softener is intended to encompass relatively coarser granules varying in size from about 150 to 2,000 microns as well as finer powder having a size as small as 30 to 50 microns.
The term “fabric softener” is used herein for purposes of convenience to refer to materials which provide softening and/or conditioning benefits to fabrics in the wash cycle of a home or automatic laundering machine.
The compacted granular fabric softener composition of the invention is comprised of a “softening clay component” which is a term used herein to refer to a fabric softening clay used by itself or optionally in combination with an organic fatty softening material. Especially preferred fabric softeners comprise a clay mineral softener, such as bentonite, in combination with a pentaerythritol ester compound as further described herein. Useful combinations of such softener may vary from about 80%, to about 90%, by weight, of clay, and from about 10% to about 20%, by weight, of fatty softening material such as a pentaerythritol compound (often abbreviated herein as “PEC”).
It has been discovered that the amount of moisture in the powder of the clay component and in the compacted softener composition significantly affect the deposition of residue on the washed fabrics. Accordingly, the preferred amount of moisture in the clay component is from about 3.5% to about 7.5%, by weight, and the total amount of moisture in the compacted fabric softener composition is from about 3% to about 15%, by weight.
In accordance with the process aspect of the invention there is provided a process for softening or conditioning laundry which comprises contacting the laundry with an effective amount of the unit dose laundry composition defined above.
DETAILED DESCRIPTION OF THE INVENTION
The clays that are useful components of the invented products include the montmorillonite-containing clays which have swelling properties (in water) and which are of smectite structure, so that they deposit on fibrous materials, especially cotton and cotton/synthetic blends, such as cotton/polyester, to give such fibers and fabrics made from them a surface lubricity or softness. The best of the smectite clays for use in the present invention is
Cao Hoai-Chau
Epp Jeffrey T.
Farooq Amjad
Gourgue Alain
Jacques Alain
Colgate-Palmolive Company
Hardee John R.
Lieberman Bernard
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