Chemistry: electrical and wave energy – Apparatus – Electrolytic
Reexamination Certificate
1999-06-17
2001-03-13
Bell, Bruce F. (Department: 1741)
Chemistry: electrical and wave energy
Apparatus
Electrolytic
C204S232000, C204S242000
Reexamination Certificate
active
06200437
ABSTRACT:
The present invention relates to an anti-corrosion wall covering for side walls in apparatus designed to collect chlorine-containing process gases, in particular in electrolytic cells. The covering is detachable and is suitable in particular for use in new and used side pieces of electrolytic cells operating according to the amalgam process.
BACKGROUND OF THE INVENTION
Various methods are known for covering side walls of electrolytic cells used in the amalgam process, which are generally made of metal. A non-detachable covering of rubber (synthetic or natural rubber) is generally applied.
The non-detachable rubber covering is in other cases provided with an additionally bonded sheet of for example ethylene-propylene-terpolymer (see for example U.S. Pat. No. 3 450 621).
On rubber-covered side pieces dioxin-containing and furan-containing reaction products are in certain circumstances formed by reaction with chlorine gas. These are undesirable by-products on account of their toxicity, which have to be removed at great expense. When a side piece of an electrolytic apparatus is to be re-covered, the existing rubber covering must first of all be removed. This is normally achieved by cooling the rubber covering to a very low temperature, whereupon the covering becomes brittle and can then be mechanically removed, for example by chiselling off the adhering rubber residues.
A side piece covering comprising a combination of rubber and an additional polymer layer as described above is complicated to produce and is also expensive. If the rubber covering is damaged moist chlorine can come into contact with the surface of the side pieces, which are normally made of steel, and cause serious corrosion of the steel part. A proper repair welding of the bonded polymer covering is not possible in practice.
SUMMARY OF THE INVENTION
The object of the present invention is to provide coverings for used or new side pieces, for example for electrolytic cells, that do not have the disadvantages of the afore described prior art and that in particular are readily detachable for repair purposes.
This object is achieved according to the invention if the covering is made of welded or trimmed sheets of special plastics that are fastened together with a stability-imparting steel part to the floor of the apparatus.
The invention provides an anti-corrosion side wall for apparatus designed to collect chlorine-containing process gases, in particular for electrolytic cells, which is characterised in that a covering of optionally welded or trimmed sheets of polyvinylidene fluoride (PVDV), polytetrafluoroethylene-co-hexafluoropropylene (FEP), polyvinyl chloride (PVC or PVC-HT) or perfluoroalkoxy polymer (PFA) is placed, and optionally fixed with a detachable adhesive for mounting purposes, on a metal support structure of in particular steel or stainless steel that can be joined to the floor of the apparatus or further side parts by detachable securement means.
The individual plastics sheets for producing the covering may be trimmed and under optimum conditions joined to one another, for example by welding, before being mounted on the support structure. The overall surface of the metal support structure may in addition be provided with an anti-corrosion layer, for example a coating of DD paints or with epoxy resins.
Should the covering be damaged after its removal from the side piece, it can easily be repaired. The structurally determined gap between the covering and support structure furthermore enables the leak-proofness of the covering to be checked.
A thermal insulation, for example based on closed-cell polymer foams, especially polyurethane foam, is in particular additionally provided between the support structure and covering.
Although the plastics materials used according to the invention have a high coefficient of thermal expansion, tests have shown that the aforementioned plastics are particularly suitable for coverings of side pieces in electrolytic cells.
The proposed detachable side parts are used in particular in electrolytic cells for producing chlorine according to the amalgam process.
Sensors may be installed in the space between the covering and the side wall support structure, which permit testing for leaks of, for example, escaping chlorine or salt solution.
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Clasen Peter
Dykrzak Horst
Venghaus Stefan
Bayer Aktiengesellschaft
Bell Bruce F.
Norris & McLaughlin & Marcus
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